Five-membered rings with two nonadjacent heteroatoms with at least one other element

R Alan Aitken; Fiona Marie Fotherby

doi:10.1016/B978-0-12-818655-8.00112-8

Five-membered rings with two nonadjacent heteroatoms with at least one other element

R Alan Aitken, Fiona Marie Fotherby

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Abstract

Developments in the chemistry of five-membered ring heterocycles containing two nonadjacent heteroatoms, with at least one silicon or germanium, in the period 2008–2020 are reviewed. Application of theoretical and structural methods to these compounds is described including X-ray structure determination and ²⁹Si NMR. The major reactions of azasiloline and oxasiloline systems as well as heavier chalcogen and benzo analogues and disilole systems are discussed. This is followed by a briefer discussion of azagermoline, phosphagermoline and oxagermoline reactivity. Methods for the synthesis of both silicon and germanium systems are systematically covered. The systems containing germanium have mainly been reported recently and were hardly included in previous editions of Comprehensive Heterocyclic Chemistry.

Original language	English
Title of host publication	Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021
Subtitle of host publication	Volume 4: Five-membered rings with two heteroatoms, and their fused carbocyclic derivatives
Editors	R. A. Aitken
Place of Publication	Amsterdam
Publisher	Elsevier (incl. Pergamon )
Chapter	4.20
Pages	1133-1145
Number of pages	13
ISBN (Electronic)	9780128186565
ISBN (Print)	9780323912679, 9780128186558
DOIs	https://doi.org/10.1016/B978-0-12-818655-8.00112-8
Publication status	Published - 23 Nov 2021

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10.1016/B978-0-12-818655-8.00112-8

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Aitken, R. A., & Fotherby, F. M. (2021). Five-membered rings with two nonadjacent heteroatoms with at least one other element. In R. A. Aitken (Ed.), Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021: Volume 4: Five-membered rings with two heteroatoms, and their fused carbocyclic derivatives (pp. 1133-1145). Elsevier (incl. Pergamon ). https://doi.org/10.1016/B978-0-12-818655-8.00112-8

Aitken, R Alan ; Fotherby, Fiona Marie. / Five-membered rings with two nonadjacent heteroatoms with at least one other element. Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021: Volume 4: Five-membered rings with two heteroatoms, and their fused carbocyclic derivatives. editor / R. A. Aitken. Amsterdam : Elsevier (incl. Pergamon ), 2021. pp. 1133-1145

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abstract = "Developments in the chemistry of five-membered ring heterocycles containing two nonadjacent heteroatoms, with at least one silicon or germanium, in the period 2008–2020 are reviewed. Application of theoretical and structural methods to these compounds is described including X-ray structure determination and 29Si NMR. The major reactions of azasiloline and oxasiloline systems as well as heavier chalcogen and benzo analogues and disilole systems are discussed. This is followed by a briefer discussion of azagermoline, phosphagermoline and oxagermoline reactivity. Methods for the synthesis of both silicon and germanium systems are systematically covered. The systems containing germanium have mainly been reported recently and were hardly included in previous editions of Comprehensive Heterocyclic Chemistry.",

author = "Aitken, {R Alan} and Fotherby, {Fiona Marie}",

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Aitken, RA & Fotherby, FM 2021, Five-membered rings with two nonadjacent heteroatoms with at least one other element. in RA Aitken (ed.), Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021: Volume 4: Five-membered rings with two heteroatoms, and their fused carbocyclic derivatives. Elsevier (incl. Pergamon ), Amsterdam, pp. 1133-1145. https://doi.org/10.1016/B978-0-12-818655-8.00112-8

Five-membered rings with two nonadjacent heteroatoms with at least one other element. / Aitken, R Alan; Fotherby, Fiona Marie.
Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021: Volume 4: Five-membered rings with two heteroatoms, and their fused carbocyclic derivatives. ed. / R. A. Aitken. Amsterdam: Elsevier (incl. Pergamon ), 2021. p. 1133-1145.

Research output: Chapter in Book/Report/Conference proceeding › Chapter

TY - CHAP

T1 - Five-membered rings with two nonadjacent heteroatoms with at least one other element

AU - Aitken, R Alan

AU - Fotherby, Fiona Marie

PY - 2021/11/23

Y1 - 2021/11/23

N2 - Developments in the chemistry of five-membered ring heterocycles containing two nonadjacent heteroatoms, with at least one silicon or germanium, in the period 2008–2020 are reviewed. Application of theoretical and structural methods to these compounds is described including X-ray structure determination and 29Si NMR. The major reactions of azasiloline and oxasiloline systems as well as heavier chalcogen and benzo analogues and disilole systems are discussed. This is followed by a briefer discussion of azagermoline, phosphagermoline and oxagermoline reactivity. Methods for the synthesis of both silicon and germanium systems are systematically covered. The systems containing germanium have mainly been reported recently and were hardly included in previous editions of Comprehensive Heterocyclic Chemistry.

AB - Developments in the chemistry of five-membered ring heterocycles containing two nonadjacent heteroatoms, with at least one silicon or germanium, in the period 2008–2020 are reviewed. Application of theoretical and structural methods to these compounds is described including X-ray structure determination and 29Si NMR. The major reactions of azasiloline and oxasiloline systems as well as heavier chalcogen and benzo analogues and disilole systems are discussed. This is followed by a briefer discussion of azagermoline, phosphagermoline and oxagermoline reactivity. Methods for the synthesis of both silicon and germanium systems are systematically covered. The systems containing germanium have mainly been reported recently and were hardly included in previous editions of Comprehensive Heterocyclic Chemistry.

UR - https://doi.org/10.1016/c2013-1-23160-9

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BT - Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021

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Aitken RA, Fotherby FM. Five-membered rings with two nonadjacent heteroatoms with at least one other element. In Aitken RA, editor, Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021: Volume 4: Five-membered rings with two heteroatoms, and their fused carbocyclic derivatives. Amsterdam: Elsevier (incl. Pergamon ). 2021. p. 1133-1145 doi: 10.1016/B978-0-12-818655-8.00112-8

Five-membered rings with two nonadjacent heteroatoms with at least one other element

Abstract

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Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021: Volume 4: Five-membered rings with two heteroatoms, and their fused carbocyclic derivatives

Cite this