Five-membered rings with two adjacent heteroatoms with at least one phosphorus, arsenic, or antimony

Petr Kilian; Alice Elizabeth Martin

doi:10.1016/B978-0-12-818655-8.00114-1

Five-membered rings with two adjacent heteroatoms with at least one phosphorus, arsenic, or antimony

Petr Kilian, Alice Elizabeth Martin

School of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Abstract

Chemistry of five-membered heterocycles containing two adjacent heteroatoms, with at least one phosphorus, arsenic or antimony, is reviewed. Species possessing 6 π-electrons are included only, which requires that at least one of the pnictogen (P, As, Sb) ring atom is two coordinate. Both neutral and anionic species are included. The timespan covered is 2008–20, with some references from 2007. Structural (single crystal X-ray diffraction) and theoretical studies of these compounds are discussed, with a number of 31P NMR data listed. The reactivity and synthesis are systematically covered. The reactivity is dominated by cycloadditions and coordination chemistry, with 1,2-diphospholes, 1,2-diphospholides, 1,2-azaphospholes and 1,2-azaarsoles dominating this area of chemistry.

Original language	English
Title of host publication	Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021
Subtitle of host publication	Volume 4: Five-membered rings with two heteroatoms, and their fused carbocyclic derivatives
Editors	R.A. Aitken
Place of Publication	Amsterdam
Publisher	Elsevier Inc.
Chapter	4.15
Pages	1034-1060
Number of pages	27
ISBN (Electronic)	9780128186565
ISBN (Print)	9780128186558, 9780323912679
DOIs	https://doi.org/10.1016/B978-0-12-818655-8.00114-1
Publication status	Published - 23 Nov 2021

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10.1016/B978-0-12-818655-8.00114-1

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Kilian, P., & Martin, A. E. (2021). Five-membered rings with two adjacent heteroatoms with at least one phosphorus, arsenic, or antimony. In R. A. Aitken (Ed.), Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021: Volume 4: Five-membered rings with two heteroatoms, and their fused carbocyclic derivatives (pp. 1034-1060). Elsevier Inc.. https://doi.org/10.1016/B978-0-12-818655-8.00114-1

Kilian, Petr ; Martin, Alice Elizabeth. / Five-membered rings with two adjacent heteroatoms with at least one phosphorus, arsenic, or antimony. Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021: Volume 4: Five-membered rings with two heteroatoms, and their fused carbocyclic derivatives. editor / R.A. Aitken. Amsterdam : Elsevier Inc., 2021. pp. 1034-1060

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abstract = "Chemistry of five-membered heterocycles containing two adjacent heteroatoms, with at least one phosphorus, arsenic or antimony, is reviewed. Species possessing 6 π-electrons are included only, which requires that at least one of the pnictogen (P, As, Sb) ring atom is two coordinate. Both neutral and anionic species are included. The timespan covered is 2008–20, with some references from 2007. Structural (single crystal X-ray diffraction) and theoretical studies of these compounds are discussed, with a number of 31P NMR data listed. The reactivity and synthesis are systematically covered. The reactivity is dominated by cycloadditions and coordination chemistry, with 1,2-diphospholes, 1,2-diphospholides, 1,2-azaphospholes and 1,2-azaarsoles dominating this area of chemistry.",

author = "Petr Kilian and Martin, {Alice Elizabeth}",

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Kilian, P & Martin, AE 2021, Five-membered rings with two adjacent heteroatoms with at least one phosphorus, arsenic, or antimony. in RA Aitken (ed.), Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021: Volume 4: Five-membered rings with two heteroatoms, and their fused carbocyclic derivatives. Elsevier Inc., Amsterdam, pp. 1034-1060. https://doi.org/10.1016/B978-0-12-818655-8.00114-1

Five-membered rings with two adjacent heteroatoms with at least one phosphorus, arsenic, or antimony. / Kilian, Petr; Martin, Alice Elizabeth.
Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021: Volume 4: Five-membered rings with two heteroatoms, and their fused carbocyclic derivatives. ed. / R.A. Aitken. Amsterdam: Elsevier Inc., 2021. p. 1034-1060.

Research output: Chapter in Book/Report/Conference proceeding › Chapter

TY - CHAP

T1 - Five-membered rings with two adjacent heteroatoms with at least one phosphorus, arsenic, or antimony

AU - Kilian, Petr

AU - Martin, Alice Elizabeth

PY - 2021/11/23

Y1 - 2021/11/23

N2 - Chemistry of five-membered heterocycles containing two adjacent heteroatoms, with at least one phosphorus, arsenic or antimony, is reviewed. Species possessing 6 π-electrons are included only, which requires that at least one of the pnictogen (P, As, Sb) ring atom is two coordinate. Both neutral and anionic species are included. The timespan covered is 2008–20, with some references from 2007. Structural (single crystal X-ray diffraction) and theoretical studies of these compounds are discussed, with a number of 31P NMR data listed. The reactivity and synthesis are systematically covered. The reactivity is dominated by cycloadditions and coordination chemistry, with 1,2-diphospholes, 1,2-diphospholides, 1,2-azaphospholes and 1,2-azaarsoles dominating this area of chemistry.

AB - Chemistry of five-membered heterocycles containing two adjacent heteroatoms, with at least one phosphorus, arsenic or antimony, is reviewed. Species possessing 6 π-electrons are included only, which requires that at least one of the pnictogen (P, As, Sb) ring atom is two coordinate. Both neutral and anionic species are included. The timespan covered is 2008–20, with some references from 2007. Structural (single crystal X-ray diffraction) and theoretical studies of these compounds are discussed, with a number of 31P NMR data listed. The reactivity and synthesis are systematically covered. The reactivity is dominated by cycloadditions and coordination chemistry, with 1,2-diphospholes, 1,2-diphospholides, 1,2-azaphospholes and 1,2-azaarsoles dominating this area of chemistry.

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SP - 1034

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BT - Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021

A2 - Aitken, R.A.

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Kilian P, Martin AE. Five-membered rings with two adjacent heteroatoms with at least one phosphorus, arsenic, or antimony. In Aitken RA, editor, Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021: Volume 4: Five-membered rings with two heteroatoms, and their fused carbocyclic derivatives. Amsterdam: Elsevier Inc. 2021. p. 1034-1060 doi: 10.1016/B978-0-12-818655-8.00114-1

Five-membered rings with two adjacent heteroatoms with at least one phosphorus, arsenic, or antimony

Abstract

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Comprehensive heterocyclic chemistry IV - a review of the literature 2008-2021: Volume 4: Five-membered rings with two heteroatoms, and their fused carbocyclic derivatives

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