Five-membered arsenic-sulfur-nitrogen heterocycles, RAs(S2N2) (R = Me, Et, iPr, tBu, Ph, Mes)

Vit Matuska; Alexandra M. Z. Slawin; J. Derek Woollins

doi:10.1021/ic1000107

Five-membered arsenic-sulfur-nitrogen heterocycles, RAs(S₂N₂) (R = Me, Et, ⁱPr, ^tBu, Ph, Mes)

Vit Matuska, Alexandra M. Z. Slawin, J. Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

A series of 5-alkyl/aryl-1,3 lambda(4)delta(2),2,4,5-dithiadiazarsoles RAs(S2N2) (R = Me, Et, Pr-i, Bu-t, Ph, Mes) were prepared by a ligand exchange between [(Bu2Sn)-Bu-n(S2N2)](2) and the corresponding organodihalogenoarsines RAsX2 (X = Cl, I). All products were characterized by NMR, IR, and Raman spectroscopies and mass spectrometry. The crystal structures of the aryldithiadiazarsoles (R = Ph, Mes) were determined.

Original language	English
Pages (from-to)	3064-3069
Number of pages	6
Journal	Inorganic Chemistry
Volume	49
Issue number	6
Early online date	8 Feb 2010
DOIs	https://doi.org/10.1021/ic1000107
Publication status	Published - 15 Mar 2010

Keywords

Ray structure-analysis
Vibrational-spectra
Raman-spectra
Crystal-structure
Roeskys ketone
Complexes
Ring
Derivatives
TBUAS(NSN)2ASTBU
Verbindungen

Access to Document

10.1021/ic1000107

Arsenic vit derek
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see DOI: 10.1021/ic1000107
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Cite this

@article{255a83d977ee4904894bf6f05501c27a,

title = "Five-membered arsenic-sulfur-nitrogen heterocycles, RAs(S2N2) (R = Me, Et, iPr, tBu, Ph, Mes)",

abstract = "A series of 5-alkyl/aryl-1,3 lambda(4)delta(2),2,4,5-dithiadiazarsoles RAs(S2N2) (R = Me, Et, Pr-i, Bu-t, Ph, Mes) were prepared by a ligand exchange between [(Bu2Sn)-Bu-n(S2N2)](2) and the corresponding organodihalogenoarsines RAsX2 (X = Cl, I). All products were characterized by NMR, IR, and Raman spectroscopies and mass spectrometry. The crystal structures of the aryldithiadiazarsoles (R = Ph, Mes) were determined.",

keywords = "Ray structure-analysis, Vibrational-spectra, Raman-spectra, Crystal-structure, Roeskys ketone, Complexes, Ring, Derivatives, TBUAS(NSN)2ASTBU, Verbindungen",

author = "Vit Matuska and Slawin, {Alexandra M. Z.} and Woollins, {J. Derek}",

note = "This work was carried out with the financial support of Engineering and Physical Sciences Research Council (EPSRC), U.K. ",

year = "2010",

month = mar,

day = "15",

doi = "10.1021/ic1000107",

language = "English",

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TY - JOUR

T1 - Five-membered arsenic-sulfur-nitrogen heterocycles, RAs(S2N2) (R = Me, Et, iPr, tBu, Ph, Mes)

AU - Matuska, Vit

AU - Slawin, Alexandra M. Z.

AU - Woollins, J. Derek

N1 - This work was carried out with the financial support of Engineering and Physical Sciences Research Council (EPSRC), U.K.

PY - 2010/3/15

Y1 - 2010/3/15

N2 - A series of 5-alkyl/aryl-1,3 lambda(4)delta(2),2,4,5-dithiadiazarsoles RAs(S2N2) (R = Me, Et, Pr-i, Bu-t, Ph, Mes) were prepared by a ligand exchange between [(Bu2Sn)-Bu-n(S2N2)](2) and the corresponding organodihalogenoarsines RAsX2 (X = Cl, I). All products were characterized by NMR, IR, and Raman spectroscopies and mass spectrometry. The crystal structures of the aryldithiadiazarsoles (R = Ph, Mes) were determined.

AB - A series of 5-alkyl/aryl-1,3 lambda(4)delta(2),2,4,5-dithiadiazarsoles RAs(S2N2) (R = Me, Et, Pr-i, Bu-t, Ph, Mes) were prepared by a ligand exchange between [(Bu2Sn)-Bu-n(S2N2)](2) and the corresponding organodihalogenoarsines RAsX2 (X = Cl, I). All products were characterized by NMR, IR, and Raman spectroscopies and mass spectrometry. The crystal structures of the aryldithiadiazarsoles (R = Ph, Mes) were determined.

KW - Ray structure-analysis

KW - Vibrational-spectra

KW - Raman-spectra

KW - Crystal-structure

KW - Roeskys ketone

KW - Complexes

KW - Ring

KW - Derivatives

KW - TBUAS(NSN)2ASTBU

KW - Verbindungen

U2 - 10.1021/ic1000107

DO - 10.1021/ic1000107

M3 - Article

SN - 0020-1669

VL - 49

SP - 3064

EP - 3069

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 6

ER -