First synthesis of a unique dilead Schiff base complex

P Bhattacharyya; J Parr; AT Ross; Alexandra Martha Zoya Slawin

doi:10.1039/a806058d

First synthesis of a unique dilead Schiff base complex

P Bhattacharyya, J Parr, AT Ross, Alexandra Martha Zoya Slawin

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Abstract

The reaction of the tripodal Schiff base ligand N[CH2CH2N=C(H)C6H3(OMe)-3-(OH)-2](3) (H3L) with lead(II) chloride in methanol in the presence of a base led to the bimetallic complex [Pb2L]Cl 1 in good yield; the cation was characterised crystallographically as the perchlorate salt 2, revealing dissimilar environments for the Pb(II) centres with one lead lying within the central cavity of (L)(3-) and the second bound externally to the three phenolate oxygens of the ligand.

Original language	English
Pages (from-to)	3149-3150
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	19
DOIs	https://doi.org/10.1039/a806058d
Publication status	Published - 7 Oct 1998

Keywords

LIGANDS
LEAD(II)

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title = "First synthesis of a unique dilead Schiff base complex",

abstract = "The reaction of the tripodal Schiff base ligand N[CH2CH2N=C(H)C6H3(OMe)-3-(OH)-2](3) (H3L) with lead(II) chloride in methanol in the presence of a base led to the bimetallic complex [Pb2L]Cl 1 in good yield; the cation was characterised crystallographically as the perchlorate salt 2, revealing dissimilar environments for the Pb(II) centres with one lead lying within the central cavity of (L)(3-) and the second bound externally to the three phenolate oxygens of the ligand.",

keywords = "LIGANDS, LEAD(II)",

author = "P Bhattacharyya and J Parr and AT Ross and Slawin, \{Alexandra Martha Zoya\}",

year = "1998",

month = oct,

day = "7",

doi = "10.1039/a806058d",

language = "English",

pages = "3149--3150",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

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T1 - First synthesis of a unique dilead Schiff base complex

AU - Bhattacharyya, P

AU - Parr, J

AU - Ross, AT

AU - Slawin, Alexandra Martha Zoya

PY - 1998/10/7

Y1 - 1998/10/7

N2 - The reaction of the tripodal Schiff base ligand N[CH2CH2N=C(H)C6H3(OMe)-3-(OH)-2](3) (H3L) with lead(II) chloride in methanol in the presence of a base led to the bimetallic complex [Pb2L]Cl 1 in good yield; the cation was characterised crystallographically as the perchlorate salt 2, revealing dissimilar environments for the Pb(II) centres with one lead lying within the central cavity of (L)(3-) and the second bound externally to the three phenolate oxygens of the ligand.

AB - The reaction of the tripodal Schiff base ligand N[CH2CH2N=C(H)C6H3(OMe)-3-(OH)-2](3) (H3L) with lead(II) chloride in methanol in the presence of a base led to the bimetallic complex [Pb2L]Cl 1 in good yield; the cation was characterised crystallographically as the perchlorate salt 2, revealing dissimilar environments for the Pb(II) centres with one lead lying within the central cavity of (L)(3-) and the second bound externally to the three phenolate oxygens of the ligand.

KW - LIGANDS

KW - LEAD(II)

UR - https://www.scopus.com/pages/publications/33748498242

U2 - 10.1039/a806058d

DO - 10.1039/a806058d

M3 - Article

SN - 0300-9246

SP - 3149

EP - 3150

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 19

ER -

First synthesis of a unique dilead Schiff base complex

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