TY - JOUR
T1 - First example of an infinite polybromide 2D-network.
AU - Aragoni, MC
AU - Arca, M
AU - Devillanova, FA
AU - Isaia, F
AU - Lippolis, V
AU - Mancini, A
AU - Pala, L
AU - Slawin, Alexandra Martha Zoya
AU - Woollins, John Derek
PY - 2003/7
Y1 - 2003/7
N2 - The reaction of the neutral dithiolene [Pd(Et(2)timdt)(2)] (Et(2)timdt = formally monoreduced diethylimidazolidine-2,4,5- trithione) with an excess of Br-2 yielded few crystals of [1Et.2Br](2+)(Br-)(2)(Br-2)(3) as a by-product (1(Et) = 4,5,9,10- tetrathiocino[ 1,2-b: 5,6-b']-1,3,6,8-tetraethyl-diimidazolyl-2,7- dithione); X-ray diffraction analysis showed that this compound represents the first example of a polybromide 2D-network templated by [1(Et).2Br](+2) dications, and featuring all the Br-Br distances shorter than those found in solid state bromine.
AB - The reaction of the neutral dithiolene [Pd(Et(2)timdt)(2)] (Et(2)timdt = formally monoreduced diethylimidazolidine-2,4,5- trithione) with an excess of Br-2 yielded few crystals of [1Et.2Br](2+)(Br-)(2)(Br-2)(3) as a by-product (1(Et) = 4,5,9,10- tetrathiocino[ 1,2-b: 5,6-b']-1,3,6,8-tetraethyl-diimidazolyl-2,7- dithione); X-ray diffraction analysis showed that this compound represents the first example of a polybromide 2D-network templated by [1(Et).2Br](+2) dications, and featuring all the Br-Br distances shorter than those found in solid state bromine.
KW - CRYSTAL-STRUCTURES
KW - POLYIODIDE NETWORKS
KW - PHENYLTRIMETHYLAMMONIUM SALTS
KW - COMPLEXES
KW - BROMINE
UR - http://www.scopus.com/inward/record.url?scp=0041733912&partnerID=8YFLogxK
UR - http://www.rsc.org/Publishing/Journals/CC/article.asp?doi=b306841b
U2 - 10.1039/b306841b
DO - 10.1039/b306841b
M3 - Article
SN - 1359-7345
VL - 2003
SP - 2226
EP - 2227
JO - Chemical Communications
JF - Chemical Communications
IS - 17
ER -