First EPR Characterisation of the Structures and Reactivities of alpha- and beta-Boryl Radicals Derived from Boronic Esters

A McCarroll; John Christopher Walton; R Nziengui; B Carboni

First EPR Characterisation of the Structures and Reactivities of alpha- and beta-Boryl Radicals Derived from Boronic Esters

A McCarroll, John Christopher Walton, R Nziengui, B Carboni

Research output: Other contribution

Abstract

The first EPR observations of carbon-centred radicals with alpha- and beta-boronic ester substitutents indicated moderate thermodynamic stabilisation for the former whereas the latter had an inclination towards beta-scission.

Original language	English
Publication status	Published - 7 Nov 1997

Keywords

PARAMAGNETIC-RES SPECTROSCOPY
ELECTRON-SPIN RESONANCE
ORGANOBORON CHEMISTRY
ALKYL RADICALS

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@misc{108210b23f9f4d858739ea4df1147aff,

title = "First EPR Characterisation of the Structures and Reactivities of alpha- and beta-Boryl Radicals Derived from Boronic Esters",

abstract = "The first EPR observations of carbon-centred radicals with alpha- and beta-boronic ester substitutents indicated moderate thermodynamic stabilisation for the former whereas the latter had an inclination towards beta-scission.",

keywords = "PARAMAGNETIC-RES SPECTROSCOPY, ELECTRON-SPIN RESONANCE, ORGANOBORON CHEMISTRY, ALKYL RADICALS",

author = "A McCarroll and Walton, {John Christopher} and R Nziengui and B Carboni",

note = "Chem Commun",

year = "1997",

month = nov,

day = "7",

language = "English",

type = "Other",

}

TY - GEN

T1 - First EPR Characterisation of the Structures and Reactivities of alpha- and beta-Boryl Radicals Derived from Boronic Esters

AU - McCarroll, A

AU - Walton, John Christopher

AU - Nziengui, R

AU - Carboni, B

N1 - Chem Commun

PY - 1997/11/7

Y1 - 1997/11/7

N2 - The first EPR observations of carbon-centred radicals with alpha- and beta-boronic ester substitutents indicated moderate thermodynamic stabilisation for the former whereas the latter had an inclination towards beta-scission.

AB - The first EPR observations of carbon-centred radicals with alpha- and beta-boronic ester substitutents indicated moderate thermodynamic stabilisation for the former whereas the latter had an inclination towards beta-scission.

KW - PARAMAGNETIC-RES SPECTROSCOPY

KW - ELECTRON-SPIN RESONANCE

KW - ORGANOBORON CHEMISTRY

KW - ALKYL RADICALS

UR - http://www.scopus.com/inward/record.url?scp=0342646316&partnerID=8YFLogxK

M3 - Other contribution

ER -

First EPR Characterisation of the Structures and Reactivities of alpha- and beta-Boryl Radicals Derived from Boronic Esters

Abstract

Keywords

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