Ferrocenecarboxylic acid-1,4-diazabicyclo[2.2.2]octane (2/1): sheets built from O-H ... N and C-H ... O hydrogen bonds

C M  Zakaria; G  Ferguson; A J  Lough; C  Glidewell

Ferrocenecarboxylic acid-1,4-diazabicyclo[2.2.2]octane (2/1): sheets built from O-H ... N and C-H ... O hydrogen bonds

C M Zakaria, G Ferguson, A J Lough, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, 2[Fe(C5H5)(C6H5O2)].C6H12N2, the molecular components are linked into finite three-component aggregates by strong O-H . . . N hydrogen bonds [O . . . N 2.578 (4) and 2.604 (5) Angstrom; O-H . . . N 170 (5) and 174 (6)degrees]; these aggregates are further linked by C-H . . . O hydrogen bonds [C . . . O 3.327 (5)-3.401 (5) Angstrom; C-H . . . O 149-157 degrees] into continuous sheets in the form of (6,3) nets.

Original language	English
Pages (from-to)	687-689
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	57
Publication status	Published - Jun 2001

Keywords

SUPRAMOLECULAR STRUCTURES
ORGANIC DIAMINES
3-DIMENSION
2-DIMENSION
SALTS
ACID

Cite this

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title = "Ferrocenecarboxylic acid-1,4-diazabicyclo[2.2.2]octane (2/1): sheets built from O-H ... N and C-H ... O hydrogen bonds",

abstract = "In the title compound, 2[Fe(C5H5)(C6H5O2)].C6H12N2, the molecular components are linked into finite three-component aggregates by strong O-H . . . N hydrogen bonds [O . . . N 2.578 (4) and 2.604 (5) Angstrom; O-H . . . N 170 (5) and 174 (6)degrees]; these aggregates are further linked by C-H . . . O hydrogen bonds [C . . . O 3.327 (5)-3.401 (5) Angstrom; C-H . . . O 149-157 degrees] into continuous sheets in the form of (6,3) nets.",

keywords = "SUPRAMOLECULAR STRUCTURES, ORGANIC DIAMINES, 3-DIMENSION, 2-DIMENSION, SALTS, ACID",

author = "Zakaria, \{C M\} and G Ferguson and Lough, \{A J\} and C Glidewell",

year = "2001",

month = jun,

language = "English",

volume = "57",

pages = "687--689",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - Ferrocenecarboxylic acid-1,4-diazabicyclo[2.2.2]octane (2/1): sheets built from O-H ... N and C-H ... O hydrogen bonds

AU - Zakaria, C M

AU - Ferguson, G

AU - Lough, A J

AU - Glidewell, C

PY - 2001/6

Y1 - 2001/6

N2 - In the title compound, 2[Fe(C5H5)(C6H5O2)].C6H12N2, the molecular components are linked into finite three-component aggregates by strong O-H . . . N hydrogen bonds [O . . . N 2.578 (4) and 2.604 (5) Angstrom; O-H . . . N 170 (5) and 174 (6)degrees]; these aggregates are further linked by C-H . . . O hydrogen bonds [C . . . O 3.327 (5)-3.401 (5) Angstrom; C-H . . . O 149-157 degrees] into continuous sheets in the form of (6,3) nets.

AB - In the title compound, 2[Fe(C5H5)(C6H5O2)].C6H12N2, the molecular components are linked into finite three-component aggregates by strong O-H . . . N hydrogen bonds [O . . . N 2.578 (4) and 2.604 (5) Angstrom; O-H . . . N 170 (5) and 174 (6)degrees]; these aggregates are further linked by C-H . . . O hydrogen bonds [C . . . O 3.327 (5)-3.401 (5) Angstrom; C-H . . . O 149-157 degrees] into continuous sheets in the form of (6,3) nets.

KW - SUPRAMOLECULAR STRUCTURES

KW - ORGANIC DIAMINES

KW - 3-DIMENSION

KW - 2-DIMENSION

KW - SALTS

KW - ACID

M3 - Article

SN - 1600-5759

SN - 0108-2701

VL - 57

SP - 687

EP - 689

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

Ferrocenecarboxylic acid-1,4-diazabicyclo[2.2.2]octane (2/1): sheets built from O-H ... N and C-H ... O hydrogen bonds

Abstract

Keywords

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