Facile introduction of 15N into chalcogen–nitrogen systems using 15N-labelled ammonia

V C  GINN; P F  KELLY; J D  WOOLLINS

doi:10.1039/DT9920002129

Facile introduction of 15N into chalcogen–nitrogen systems using 15N-labelled ammonia

V C GINN, P F KELLY, J D WOOLLINS

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

Reaction of N-15-labelled ammonia with a toluene solution of (EtO)2SeO under reduced pressure gives (Se4N4)-N-15; in the presence of [PtCl2(PMe2Ph)2] (with CH2Cl2 as solvent) the same reagents yield [Pt(Se2N2)-N-15 (PMe2Ph)2] whilst (NH3)-N-15, [PtCl2(PMe2Ph)2] and SOCl2 react to form [Pt(NSO)2)-N-15-(PMe2Ph)2].

Original language	English
Pages (from-to)	2129-2130
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	13
DOIs	https://doi.org/10.1039/DT9920002129
Publication status	Published - 7 Jul 1992

Keywords

COMPLEXES
LIGANDS
SE4N4

Access to Document

10.1039/DT9920002129

Cite this

@article{9096291ade4c4e08bd6f65fdfbd08cbe,

title = "Facile introduction of 15N into chalcogen–nitrogen systems using 15N-labelled ammonia",

abstract = "Reaction of N-15-labelled ammonia with a toluene solution of (EtO)2SeO under reduced pressure gives (Se4N4)-N-15; in the presence of [PtCl2(PMe2Ph)2] (with CH2Cl2 as solvent) the same reagents yield [Pt(Se2N2)-N-15 (PMe2Ph)2] whilst (NH3)-N-15, [PtCl2(PMe2Ph)2] and SOCl2 react to form [Pt(NSO)2)-N-15-(PMe2Ph)2].",

keywords = "COMPLEXES, LIGANDS, SE4N4",

author = "GINN, {V C} and KELLY, {P F} and WOOLLINS, {J D}",

year = "1992",

month = jul,

day = "7",

doi = "10.1039/DT9920002129",

language = "English",

pages = "2129--2130",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "13",

}

TY - JOUR

T1 - Facile introduction of 15N into chalcogen–nitrogen systems using 15N-labelled ammonia

AU - GINN, V C

AU - KELLY, P F

AU - WOOLLINS, J D

PY - 1992/7/7

Y1 - 1992/7/7

N2 - Reaction of N-15-labelled ammonia with a toluene solution of (EtO)2SeO under reduced pressure gives (Se4N4)-N-15; in the presence of [PtCl2(PMe2Ph)2] (with CH2Cl2 as solvent) the same reagents yield [Pt(Se2N2)-N-15 (PMe2Ph)2] whilst (NH3)-N-15, [PtCl2(PMe2Ph)2] and SOCl2 react to form [Pt(NSO)2)-N-15-(PMe2Ph)2].

AB - Reaction of N-15-labelled ammonia with a toluene solution of (EtO)2SeO under reduced pressure gives (Se4N4)-N-15; in the presence of [PtCl2(PMe2Ph)2] (with CH2Cl2 as solvent) the same reagents yield [Pt(Se2N2)-N-15 (PMe2Ph)2] whilst (NH3)-N-15, [PtCl2(PMe2Ph)2] and SOCl2 react to form [Pt(NSO)2)-N-15-(PMe2Ph)2].

KW - COMPLEXES

KW - LIGANDS

KW - SE4N4

U2 - 10.1039/DT9920002129

DO - 10.1039/DT9920002129

M3 - Comment/debate

SN - 0300-9246

SP - 2129

EP - 2130

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 13

ER -

Facile introduction of 15N into chalcogen–nitrogen systems using 15N-labelled ammonia

Abstract

Keywords

Access to Document

Fingerprint

Cite this