Facile introduction of 15N into chalcogen–nitrogen systems using 15N-labelled ammonia

V C GINN, P F KELLY, J D WOOLLINS

Research output: Contribution to journalComment/debatepeer-review

15 Citations (Scopus)

Abstract

Reaction of N-15-labelled ammonia with a toluene solution of (EtO)2SeO under reduced pressure gives (Se4N4)-N-15; in the presence of [PtCl2(PMe2Ph)2] (with CH2Cl2 as solvent) the same reagents yield [Pt(Se2N2)-N-15 (PMe2Ph)2] whilst (NH3)-N-15, [PtCl2(PMe2Ph)2] and SOCl2 react to form [Pt(NSO)2)-N-15-(PMe2Ph)2].

Original languageEnglish
Pages (from-to)2129-2130
Number of pages2
JournalJournal of the Chemical Society, Dalton Transactions
Issue number13
DOIs
Publication statusPublished - 7 Jul 1992

Keywords

  • COMPLEXES
  • LIGANDS
  • SE4N4

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