Facile chalcogenide elimination reactions: the crystal structures of [Pt{(Ph2PO)2H}{(Ph2PSeO)2H}]·1.25CHCl3 and [Pt3(Ph2PCH2CH2PPh2)3S2][(Ph2PSO)2H][OH]·0.5CH2Cl2

M J  PILKINGTON; A M Z  SLAWIN; D J  WILLIAMS; J D  WOOLLINS

doi:10.1039/dt9920002425

Facile chalcogenide elimination reactions: the crystal structures of [Pt{(Ph2PO)2H}{(Ph2PSeO)2H}]·1.25CHCl3 and [Pt3(Ph2PCH2CH2PPh2)3S2][(Ph2PSO)2H][OH]·0.5CH2Cl2

M J PILKINGTON, A M Z SLAWIN, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

Reaction of Ph2PSeOH with [PtCl2(PR3)2] (PR3 = PEt3 or PMe2Ph) gives [Pt{(Ph2PO)2H}{(Ph2PSeO)2H}] 1, whereas the analogous sulfur compound Ph2PSOH with [PtCl2(dppe)] (dppe = Ph2PCH2CH2PPh2) gives the bipyramidal Pt3S2 containing cluster [Pt3(dppe)3S2]2+.

Original language	English
Pages (from-to)	2425-2426
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	15
DOIs	https://doi.org/10.1039/dt9920002425
Publication status	Published - 7 Aug 1992

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10.1039/dt9920002425

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@article{db7bd86c64724de7bbf7f467cf30d423,

title = "Facile chalcogenide elimination reactions: the crystal structures of [Pt{(Ph2PO)2H}{(Ph2PSeO)2H}]·1.25CHCl3 and [Pt3(Ph2PCH2CH2PPh2)3S2][(Ph2PSO)2H][OH]·0.5CH2Cl2",

abstract = "Reaction of Ph2PSeOH with [PtCl2(PR3)2] (PR3 = PEt3 or PMe2Ph) gives [Pt{(Ph2PO)2H}{(Ph2PSeO)2H}] 1, whereas the analogous sulfur compound Ph2PSOH with [PtCl2(dppe)] (dppe = Ph2PCH2CH2PPh2) gives the bipyramidal Pt3S2 containing cluster [Pt3(dppe)3S2]2+.",

keywords = "COMPLEXES",

author = "PILKINGTON, {M J} and SLAWIN, {A M Z} and WILLIAMS, {D J} and WOOLLINS, {J D}",

year = "1992",

month = aug,

day = "7",

doi = "10.1039/dt9920002425",

language = "English",

pages = "2425--2426",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "15",

}

Facile chalcogenide elimination reactions: the crystal structures of [Pt{(Ph2PO)2H}{(Ph2PSeO)2H}]·1.25CHCl3 and [Pt3(Ph2PCH2CH2PPh2)3S2][(Ph2PSO)2H][OH]·0.5CH2Cl2. / PILKINGTON, M J ; SLAWIN, A M Z ; WILLIAMS, D J et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 15, 07.08.1992, p. 2425-2426.

Research output: Contribution to journal › Comment/debate › peer-review

TY - JOUR

T1 - Facile chalcogenide elimination reactions: the crystal structures of [Pt{(Ph2PO)2H}{(Ph2PSeO)2H}]·1.25CHCl3 and [Pt3(Ph2PCH2CH2PPh2)3S2][(Ph2PSO)2H][OH]·0.5CH2Cl2

AU - PILKINGTON, M J

AU - SLAWIN, A M Z

AU - WILLIAMS, D J

AU - WOOLLINS, J D

PY - 1992/8/7

Y1 - 1992/8/7

N2 - Reaction of Ph2PSeOH with [PtCl2(PR3)2] (PR3 = PEt3 or PMe2Ph) gives [Pt{(Ph2PO)2H}{(Ph2PSeO)2H}] 1, whereas the analogous sulfur compound Ph2PSOH with [PtCl2(dppe)] (dppe = Ph2PCH2CH2PPh2) gives the bipyramidal Pt3S2 containing cluster [Pt3(dppe)3S2]2+.

AB - Reaction of Ph2PSeOH with [PtCl2(PR3)2] (PR3 = PEt3 or PMe2Ph) gives [Pt{(Ph2PO)2H}{(Ph2PSeO)2H}] 1, whereas the analogous sulfur compound Ph2PSOH with [PtCl2(dppe)] (dppe = Ph2PCH2CH2PPh2) gives the bipyramidal Pt3S2 containing cluster [Pt3(dppe)3S2]2+.

KW - COMPLEXES

U2 - 10.1039/dt9920002425

DO - 10.1039/dt9920002425

M3 - Comment/debate

SN - 0300-9246

SP - 2425

EP - 2426

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 15

ER -

Facile chalcogenide elimination reactions: the crystal structures of [Pt{(Ph2PO)2H}{(Ph2PSeO)2H}]·1.25CHCl3 and [Pt3(Ph2PCH2CH2PPh2)3S2][(Ph2PSO)2H][OH]·0.5CH2Cl2

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