Facile chalcogenide elimination reactions: the crystal structures of [Pt{(Ph2PO)2H}{(Ph2PSeO)2H}]·1.25CHCl3 and [Pt3(Ph2PCH2CH2PPh2)3S2][(Ph2PSO)2H][OH]·0.5CH2Cl2

M J PILKINGTON, A M Z SLAWIN, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journalComment/debatepeer-review

32 Citations (Scopus)

Abstract

Reaction of Ph2PSeOH with [PtCl2(PR3)2] (PR3 = PEt3 or PMe2Ph) gives [Pt{(Ph2PO)2H}{(Ph2PSeO)2H}] 1, whereas the analogous sulfur compound Ph2PSOH with [PtCl2(dppe)] (dppe = Ph2PCH2CH2PPh2) gives the bipyramidal Pt3S2 containing cluster [Pt3(dppe)3S2]2+.

Original languageEnglish
Pages (from-to)2425-2426
Number of pages2
JournalJournal of the Chemical Society, Dalton Transactions
Issue number15
DOIs
Publication statusPublished - 7 Aug 1992

Keywords

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