Exploring the Coordination of Cyclic Selenoureas to Gold (I)

David James Nelson; Fady Nahra; David B. Cordes; Alexandra Martha Zoya Slawin; Steven Patrick Nolan

doi:10.1021/om500610w

Exploring the Coordination of Cyclic Selenoureas to Gold (I)

David James Nelson, Fady Nahra, David B. Cordes, Alexandra Martha Zoya Slawin, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

NHC-derived selenoureas, which are useful for the quantification of NHC electronic properties, are deployed as ligands for Au(I). Surprisingly, while some compounds led to the expected [AuCl(SeUr)] species, selenoureas derived from more π-accepting NHCs unexpectedly furnished crystals of the corresponding [Au(SeUr)2][AuCl2] species, in which ligand rearrangement had occurred.

Original language	English
Pages (from-to)	3640-3645
Number of pages	6
Journal	Organometallics
Volume	33
Issue number	13
Early online date	2 Jul 2014
DOIs	https://doi.org/10.1021/om500610w
Publication status	Published - 14 Jul 2014

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10.1021/om500610w

FUNCAT: EU FP7 ERC Advanced Grant - FUNCAT - Fundamental Studies in Organometallic Chemistry and Homogeneous Catalysis
Nolan, S. (PI)
European Research Council
1/01/09 → 31/12/14
Project: Standard

Synthesis and reactivity of novel (NHC)gold(I) complexes
Patrick, S. R. (Author), Nolan, S. P. (Supervisor), 1 Dec 2014
Student thesis: Doctoral Thesis (PhD)

Cite this

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title = "Exploring the Coordination of Cyclic Selenoureas to Gold (I)",

abstract = "NHC-derived selenoureas, which are useful for the quantification of NHC electronic properties, are deployed as ligands for Au(I). Surprisingly, while some compounds led to the expected [AuCl(SeUr)] species, selenoureas derived from more π-accepting NHCs unexpectedly furnished crystals of the corresponding [Au(SeUr)2][AuCl2] species, in which ligand rearrangement had occurred.",

author = "Nelson, {David James} and Fady Nahra and Cordes, {David B.} and Slawin, {Alexandra Martha Zoya} and Nolan, {Steven Patrick}",

note = "Funding: EPSRC and the ERC (Advanced Investigator Award FUNCAT)",

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language = "English",

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T1 - Exploring the Coordination of Cyclic Selenoureas to Gold (I)

AU - Nelson, David James

AU - Nahra, Fady

AU - Cordes, David B.

AU - Slawin, Alexandra Martha Zoya

AU - Nolan, Steven Patrick

N1 - Funding: EPSRC and the ERC (Advanced Investigator Award FUNCAT)

PY - 2014/7/14

Y1 - 2014/7/14

N2 - NHC-derived selenoureas, which are useful for the quantification of NHC electronic properties, are deployed as ligands for Au(I). Surprisingly, while some compounds led to the expected [AuCl(SeUr)] species, selenoureas derived from more π-accepting NHCs unexpectedly furnished crystals of the corresponding [Au(SeUr)2][AuCl2] species, in which ligand rearrangement had occurred.

AB - NHC-derived selenoureas, which are useful for the quantification of NHC electronic properties, are deployed as ligands for Au(I). Surprisingly, while some compounds led to the expected [AuCl(SeUr)] species, selenoureas derived from more π-accepting NHCs unexpectedly furnished crystals of the corresponding [Au(SeUr)2][AuCl2] species, in which ligand rearrangement had occurred.

U2 - 10.1021/om500610w

DO - 10.1021/om500610w

M3 - Article

SN - 0276-7333

VL - 33

SP - 3640

EP - 3645

JO - Organometallics

JF - Organometallics

IS - 13

ER -

Exploring the Coordination of Cyclic Selenoureas to Gold (I)

Abstract

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Projects

FUNCAT: EU FP7 ERC Advanced Grant - FUNCAT - Fundamental Studies in Organometallic Chemistry and Homogeneous Catalysis

Student theses

Synthesis and reactivity of novel (NHC)gold(I) complexes

Cite this