Exploring the Coordination of Cyclic Selenoureas to Gold (I)

David James Nelson, Fady Nahra, David B. Cordes, Alexandra Martha Zoya Slawin, Steven Patrick Nolan

Research output: Contribution to journalArticlepeer-review

61 Citations (Scopus)

Abstract

NHC-derived selenoureas, which are useful for the quantification of NHC electronic properties, are deployed as ligands for Au(I). Surprisingly, while some compounds led to the expected [AuCl(SeUr)] species, selenoureas derived from more π-accepting NHCs unexpectedly furnished crystals of the corresponding [Au(SeUr)2][AuCl2] species, in which ligand rearrangement had occurred.
Original languageEnglish
Pages (from-to)3640-3645
Number of pages6
JournalOrganometallics
Volume33
Issue number13
Early online date2 Jul 2014
DOIs
Publication statusPublished - 14 Jul 2014

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