Exploring energy transfer in luminescent heterometallic ruthenium–iridium ion pairs

Martina Sandroni, Eli Zysman-Colman

Research output: Contribution to journalArticlepeer-review

21 Citations (Scopus)

Abstract

Here, we report the synthesis of a luminescent ion pair with the formula [Ru(dtBubpy)3][Ir(ppy)2(CN)2]2. The crystal structure of this three component, heterometallic assembly is described, along with the luminescence properties of the salt. The modulation of the energy transfer between the blue-emitting iridium complex and the red-emitting ruthenium complex is also discussed as a function of both medium and concentration.

Original languageEnglish
Pages (from-to)3676-3680
JournalDalton Transactions
Volume43
Issue number9
Early online date17 Dec 2013
DOIs
Publication statusPublished - 7 Mar 2014

Keywords

  • Soft salt
  • Ion pair
  • Ruthenium
  • Iridium
  • Energy transfer
  • Luminescence

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