Ethyne Cyclization to Benzene over Cu(110)

Julian R. Lomas, Christopher J. Baddeley, Mintcho S. Tikhov, Richard M. Lambert

Research output: Contribution to journalArticlepeer-review

77 Citations (Scopus)

Abstract

Ethyne cyclization to benzene over Cu(110) is an efficient reaction that proceeds at low temperatures with close to 100% efficiency. On the clean surface, C2H2 adsorbs into islands, there is no threshold coverage for the onset of reaction, and benzene evolution into the gas phase occurs in a single TPR peak due to a surface reaction rate limited process. In each of these four respects the behavior is very different from that found on Pd(111). Isotope tracing experiments show that cyclization occurs by an associative mechanism, and the use of cis-1,2-dichlorocyclobutene indicates that C4H4 is the key reaction intermediate, as it is on Pd(111). Additional data, including results of experiments with C8H8 and with C4H4Cl2 + C2D2, demonstrate that cyclooctatetraene is not a reaction intermediate in this system, and the possible scheme 2C2H2(a) → C4H4(a); 2C4H4(a) → C8H8(a); C8H8(a) → C6H6(a) + C2H2(a) is ruled out. The mechanism 2C2H2(a) → C4H4(a); C4H4(a) + C2H2(a) → C6H6(a) is established, and it is shown that the first step is rate limiting overall.

Original languageEnglish
Pages (from-to)3048-3053
Number of pages6
JournalLangmuir
Volume11
Issue number8
DOIs
Publication statusPublished - 1 Aug 1995

Fingerprint

Dive into the research topics of 'Ethyne Cyclization to Benzene over Cu(110)'. Together they form a unique fingerprint.

Cite this