Ethyl N-[2-(hydroxyacetyl)phenyl]carbamate, ethyl N-[2-(hydroxyacetyl)-4-iodophenyl]carbamate and ethyl N-[2-(hydroxyacetyl)-4-methylphenyl] carbamate

Simon J. Garden; Marilza B. Correa; Angelo C. Pinto; James L. Wardell; John N. Low; Christopher Glidewell

doi:10.1107/S0108270107008682

Ethyl N-[2-(hydroxyacetyl)phenyl]carbamate, ethyl N-[2-(hydroxyacetyl)-4-iodophenyl]carbamate and ethyl N-[2-(hydroxyacetyl)-4-methylphenyl] carbamate

Simon J. Garden, Marilza B. Correa, Angelo C. Pinto, James L. Wardell, John N. Low, Christopher Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In ethyl N-[2-(hydroxyacetyl) phenyl] carbamate, C11H13NO4, all of the non-H atoms lie on a mirror plane in the space group Pnma; the molecules are linked into simple chains by a single C-(HO)-O-... hydrogen bond. The molecules of ethyl N-[ 2(hydroxyacetyl)-4-iodophenyl] carbamate, C11H12INO4, are linked into sheets by a combination of O-(HI)-I-... and C-(HO)-O-... hydrogen bonds and a dipolar (IO)-O-... contact. Ethyl N-[2-(hydroxyacetyl)-4-methylphenyl] carbamate, C12H15NO4, crystallizes with Z' = 2 in the space group P1; pairs of molecules are weakly linked by an O-(HO)-O-... hydrogen bond and these aggregates are linked into chains by two independent aromatic pi-pi stacking interactions.

Original language	English
Number of pages	5
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	63
DOIs	https://doi.org/10.1107/S0108270107008682
Publication status	Published - Apr 2007

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@article{5a467dc3a2e94a249d62cd77c33a5e7c,

title = "Ethyl N-[2-(hydroxyacetyl)phenyl]carbamate, ethyl N-[2-(hydroxyacetyl)-4-iodophenyl]carbamate and ethyl N-[2-(hydroxyacetyl)-4-methylphenyl] carbamate",

abstract = "In ethyl N-[2-(hydroxyacetyl) phenyl] carbamate, C11H13NO4, all of the non-H atoms lie on a mirror plane in the space group Pnma; the molecules are linked into simple chains by a single C-(HO)-O-... hydrogen bond. The molecules of ethyl N-[ 2(hydroxyacetyl)-4-iodophenyl] carbamate, C11H12INO4, are linked into sheets by a combination of O-(HI)-I-... and C-(HO)-O-... hydrogen bonds and a dipolar (IO)-O-... contact. Ethyl N-[2-(hydroxyacetyl)-4-methylphenyl] carbamate, C12H15NO4, crystallizes with Z' = 2 in the space group P1; pairs of molecules are weakly linked by an O-(HO)-O-... hydrogen bond and these aggregates are linked into chains by two independent aromatic pi-pi stacking interactions.",

author = "Garden, {Simon J.} and Correa, {Marilza B.} and Pinto, {Angelo C.} and Wardell, {James L.} and Low, {John N.} and Christopher Glidewell",

year = "2007",

month = apr,

doi = "10.1107/S0108270107008682",

language = "English",

volume = "63",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

}

Ethyl N-[2-(hydroxyacetyl)phenyl]carbamate, ethyl N-[2-(hydroxyacetyl)-4-iodophenyl]carbamate and ethyl N-[2-(hydroxyacetyl)-4-methylphenyl] carbamate. / Garden, Simon J.; Correa, Marilza B.; Pinto, Angelo C. et al.
In: Acta Crystallographica Section C-Crystal Structure Communications, Vol. 63, 04.2007.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Ethyl N-[2-(hydroxyacetyl)phenyl]carbamate, ethyl N-[2-(hydroxyacetyl)-4-iodophenyl]carbamate and ethyl N-[2-(hydroxyacetyl)-4-methylphenyl] carbamate

AU - Garden, Simon J.

AU - Correa, Marilza B.

AU - Pinto, Angelo C.

AU - Wardell, James L.

AU - Low, John N.

AU - Glidewell, Christopher

PY - 2007/4

Y1 - 2007/4

N2 - In ethyl N-[2-(hydroxyacetyl) phenyl] carbamate, C11H13NO4, all of the non-H atoms lie on a mirror plane in the space group Pnma; the molecules are linked into simple chains by a single C-(HO)-O-... hydrogen bond. The molecules of ethyl N-[ 2(hydroxyacetyl)-4-iodophenyl] carbamate, C11H12INO4, are linked into sheets by a combination of O-(HI)-I-... and C-(HO)-O-... hydrogen bonds and a dipolar (IO)-O-... contact. Ethyl N-[2-(hydroxyacetyl)-4-methylphenyl] carbamate, C12H15NO4, crystallizes with Z' = 2 in the space group P1; pairs of molecules are weakly linked by an O-(HO)-O-... hydrogen bond and these aggregates are linked into chains by two independent aromatic pi-pi stacking interactions.

AB - In ethyl N-[2-(hydroxyacetyl) phenyl] carbamate, C11H13NO4, all of the non-H atoms lie on a mirror plane in the space group Pnma; the molecules are linked into simple chains by a single C-(HO)-O-... hydrogen bond. The molecules of ethyl N-[ 2(hydroxyacetyl)-4-iodophenyl] carbamate, C11H12INO4, are linked into sheets by a combination of O-(HI)-I-... and C-(HO)-O-... hydrogen bonds and a dipolar (IO)-O-... contact. Ethyl N-[2-(hydroxyacetyl)-4-methylphenyl] carbamate, C12H15NO4, crystallizes with Z' = 2 in the space group P1; pairs of molecules are weakly linked by an O-(HO)-O-... hydrogen bond and these aggregates are linked into chains by two independent aromatic pi-pi stacking interactions.

U2 - 10.1107/S0108270107008682

DO - 10.1107/S0108270107008682

M3 - Article

SN - 1600-5759

VL - 63

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

Ethyl N-[2-(hydroxyacetyl)phenyl]carbamate, ethyl N-[2-(hydroxyacetyl)-4-iodophenyl]carbamate and ethyl N-[2-(hydroxyacetyl)-4-methylphenyl] carbamate

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