[ET]3[NICL4].H2O - A METALLIC CONDUCTOR CONTAINING THE NICL42- ANION IN A DISTORTED SQUARE-PLANAR GEOMETRY [ET = BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE]

J C FITZMAURICE, A M Z SLAWIN, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

The title compound is a metallic conductor at room temperature and its crystal structure reveals that the NiCl42- anions are not tetrahedral but have a unusual distorted square planar geometry not previously reported; the NiCl42- anions are sandwiched between lamelli of ET cations.

Original languageEnglish
Pages (from-to)1479-1480
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number19
Publication statusPublished - 7 Oct 1993

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