Estimation of bond dissociation energies, including DH°(RSCH 2-H), from barriers to internal rotation

Derek C. Nonhebel*, John C. Walton

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

33 Citations (Scopus)

Abstract

A linear correlation between C-H bond dissociation energies in molecules of the type RCH2-H and the corresponding barriers to rotation about the ·CH2-R bonds is established and used to derive the C α-H bond dissociation energy of sulphides.

Original languageEnglish
Pages (from-to)731-732
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number11
DOIs
Publication statusPublished - 1 Jan 1984

Fingerprint

Dive into the research topics of 'Estimation of bond dissociation energies, including DH°(RSCH 2-H), from barriers to internal rotation'. Together they form a unique fingerprint.

Cite this