Enhanced stereoselectivity in a di-Ru(II) complex of an achiral bis-bidentate ligand

Amlan Kumar Pal, Philippe D. Ducharme, Garry S. Hanan

Research output: Contribution to journalArticlepeer-review

23 Citations (Scopus)

Abstract

The diastereoselective formation of a meso-dinuclear Ru(II) complex of a novel bis-bidentate ligand is reported along with its electrochemical and photophysical properties. The design of the ligand, with its parallel coordination vectors, induces a diastereoselectivity of 1 : 13 : 1 [ΛΛ : (ΛΔ or ΔΛ) : ΔΔ] for the dinuclear complex.
Original languageEnglish
Pages (from-to)3303-3305
JournalChemical Communications
Volume50
Issue number25
DOIs
Publication statusPublished - 24 Dec 2013

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