Enhanced stereoselectivity in a di-Ru(II) complex of an achiral bis-bidentate ligand

Amlan Kumar Pal; Philippe D.  Ducharme; Garry S.  Hanan

doi:10.1039/C3CC47856D

Enhanced stereoselectivity in a di-Ru(II) complex of an achiral bis-bidentate ligand

Amlan Kumar Pal, Philippe D. Ducharme, Garry S. Hanan

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The diastereoselective formation of a meso-dinuclear Ru(II) complex of a novel bis-bidentate ligand is reported along with its electrochemical and photophysical properties. The design of the ligand, with its parallel coordination vectors, induces a diastereoselectivity of 1 : 13 : 1 [ΛΛ : (ΛΔ or ΔΛ) : ΔΔ] for the dinuclear complex.

Original language	English
Pages (from-to)	3303-3305
Journal	Chemical Communications
Volume	50
Issue number	25
DOIs	https://doi.org/10.1039/C3CC47856D
Publication status	Published - 24 Dec 2013

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title = "Enhanced stereoselectivity in a di-Ru(II) complex of an achiral bis-bidentate ligand",

abstract = "The diastereoselective formation of a meso-dinuclear Ru(II) complex of a novel bis-bidentate ligand is reported along with its electrochemical and photophysical properties. The design of the ligand, with its parallel coordination vectors, induces a diastereoselectivity of 1 : 13 : 1 [ΛΛ : (ΛΔ or ΔΛ) : ΔΔ] for the dinuclear complex.",

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AB - The diastereoselective formation of a meso-dinuclear Ru(II) complex of a novel bis-bidentate ligand is reported along with its electrochemical and photophysical properties. The design of the ligand, with its parallel coordination vectors, induces a diastereoselectivity of 1 : 13 : 1 [ΛΛ : (ΛΔ or ΔΛ) : ΔΔ] for the dinuclear complex.

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JO - Chemical Communications

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IS - 25

ER -

Enhanced stereoselectivity in a di-Ru(II) complex of an achiral bis-bidentate ligand

Abstract

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