Enantiomeric partitioning using fluorous biphase methodology for lipase-mediated esterifications

P Beier; David O'Hagan

doi:10.1039/b204607p

Enantiomeric partitioning using fluorous biphase methodology for lipase-mediated esterifications

Research output: Other contribution

Abstract

Lipase-catalysed (trans)esterification reactions in homogenous per-fluorocarbon-hydrocarbon solvents enabled direct enantiomeric partitioning (up to 95% ee) of the products by liquid-liquid separation.

Original language	English
DOIs	https://doi.org/10.1039/b204607p
Publication status	Published - 21 Aug 2002

Keywords

2-METHYLALKANOIC ACIDS
CATALYST SEPARATION
PHASE-SEPARATION
ORGANIC-SOLVENTS
CANDIDA-RUGOSA
ESTERIFICATION
IMMOBILIZATION
ENANTIOSELECTIVITY
HYDROFORMYLATION
DESIGN

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10.1039/b204607p

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title = "Enantiomeric partitioning using fluorous biphase methodology for lipase-mediated esterifications",

abstract = "Lipase-catalysed (trans)esterification reactions in homogenous per-fluorocarbon-hydrocarbon solvents enabled direct enantiomeric partitioning (up to 95% ee) of the products by liquid-liquid separation.",

keywords = "2-METHYLALKANOIC ACIDS, CATALYST SEPARATION, PHASE-SEPARATION, ORGANIC-SOLVENTS, CANDIDA-RUGOSA, ESTERIFICATION, IMMOBILIZATION, ENANTIOSELECTIVITY, HYDROFORMYLATION, DESIGN",

author = "P Beier and David O'Hagan",

note = "Chem Comm",

year = "2002",

month = aug,

day = "21",

doi = "10.1039/b204607p",

language = "English",

type = "Other",

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T1 - Enantiomeric partitioning using fluorous biphase methodology for lipase-mediated esterifications

AU - Beier, P

AU - O'Hagan, David

N1 - Chem Comm

PY - 2002/8/21

Y1 - 2002/8/21

N2 - Lipase-catalysed (trans)esterification reactions in homogenous per-fluorocarbon-hydrocarbon solvents enabled direct enantiomeric partitioning (up to 95% ee) of the products by liquid-liquid separation.

AB - Lipase-catalysed (trans)esterification reactions in homogenous per-fluorocarbon-hydrocarbon solvents enabled direct enantiomeric partitioning (up to 95% ee) of the products by liquid-liquid separation.

KW - 2-METHYLALKANOIC ACIDS

KW - CATALYST SEPARATION

KW - PHASE-SEPARATION

KW - ORGANIC-SOLVENTS

KW - CANDIDA-RUGOSA

KW - ESTERIFICATION

KW - IMMOBILIZATION

KW - ENANTIOSELECTIVITY

KW - HYDROFORMYLATION

KW - DESIGN

U2 - 10.1039/b204607p

DO - 10.1039/b204607p

M3 - Other contribution

ER -

Enantiomeric partitioning using fluorous biphase methodology for lipase-mediated esterifications

Abstract

Keywords

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