tert-Butyl N-(thiophen-2-yl)carbamate

Gene C. Hsu; Laci M. Singer; David B. Cordes; Michael Findlater

doi:10.1107/S160053681302196X

tert-Butyl N-(thiophen-2-yl)carbamate

Gene C. Hsu, Laci M. Singer, David B. Cordes, Michael Findlater

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, C₉H₁₃NO₂S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intramolecular C-H···O interactions in tandem with the tert-butyl groups render the packing of adjacent molecules in the [001] direction nearly perpendicular [the angle between adjacent thiophene rings is 74.83 (7)°]. An intermolecular N-H···O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin.

Original language	English
Pages (from-to)	o1413
Number of pages	1
Journal	Acta Crystallographica. Section E, Structure reports online
Volume	69
Issue number	9
DOIs	https://doi.org/10.1107/S160053681302196X
Publication status	Published - Sept 2013

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title = "tert-Butyl N-(thiophen-2-yl)carbamate",

abstract = "In the title compound, C9H13NO2S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intramolecular C-H···O interactions in tandem with the tert-butyl groups render the packing of adjacent molecules in the [001] direction nearly perpendicular [the angle between adjacent thiophene rings is 74.83 (7)°]. An intermolecular N-H···O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin.",

author = "Hsu, \{Gene C.\} and Singer, \{Laci M.\} and Cordes, \{David B.\} and Michael Findlater",

year = "2013",

month = sep,

doi = "10.1107/S160053681302196X",

language = "English",

volume = "69",

pages = "o1413",

journal = "Acta Crystallographica. Section E, Structure reports online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "9",

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T1 - tert-Butyl N-(thiophen-2-yl)carbamate

AU - Hsu, Gene C.

AU - Singer, Laci M.

AU - Cordes, David B.

AU - Findlater, Michael

PY - 2013/9

Y1 - 2013/9

N2 - In the title compound, C9H13NO2S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intramolecular C-H···O interactions in tandem with the tert-butyl groups render the packing of adjacent molecules in the [001] direction nearly perpendicular [the angle between adjacent thiophene rings is 74.83 (7)°]. An intermolecular N-H···O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin.

AB - In the title compound, C9H13NO2S, the dihedral angle between the thiophene ring and the carbamate group is 15.79 (14)°. In the crystal structure, intramolecular C-H···O interactions in tandem with the tert-butyl groups render the packing of adjacent molecules in the [001] direction nearly perpendicular [the angle between adjacent thiophene rings is 74.83 (7)°]. An intermolecular N-H···O hydrogen bond gives rise to a chain extending along [001]. The crystal studied was found to be a racemic twin.

UR - https://www.scopus.com/pages/publications/84883580789

U2 - 10.1107/S160053681302196X

DO - 10.1107/S160053681302196X

M3 - Article

SN - 1600-5368

VL - 69

SP - o1413

JO - Acta Crystallographica. Section E, Structure reports online

JF - Acta Crystallographica. Section E, Structure reports online

IS - 9

ER -

tert-Butyl N-(thiophen-2-yl)carbamate

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