Abstract
Thiol-yne click chemistry is used to covalently link a ferrocenyl derivative to the pore walls of a fully organic porous polymer coating (SURGEL). By cyclic voltammetry, it is demonstrated that the ferrocene bound to the SURGEL via a flexible alkyl linker can be reversibly reduced and oxidised. Surprisingly, when adding ferrocene as an electrolyte, a Nemstian diffusion limited process is observed. We explain this observation in terms of a high permeability of the SURGELs for ferrocene after the post synthetic modification.
Original language | English |
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Pages (from-to) | 11129-11131 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 50 |
Issue number | 76 |
DOIs | |
Publication status | Published - 2014 |
Keywords
- FRAMEWORK THIN-FILMS
- POROUS COORDINATION POLYMERS
- METAL-ORGANIC FRAMEWORKS
- CLICK CHEMISTRY