Efficient ruthenium-catalysed S-S, S-Si and S-B bond forming reactions

Jose Antonio Fernandez Salas; Simone Manzini; Steven Patrick Nolan

doi:10.1039/c3cc43145b

Efficient ruthenium-catalysed S-S, S-Si and S-B bond forming reactions

Jose Antonio Fernandez Salas, Simone Manzini, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

[RuCl(PPh3)2(3-phenylindenyl)] (1) has been shown to be an efficient catalyst in thiol dehydrogenative coupling to give disulfides. Moreover, an efficient procedure for the preparation of silylthioethers and thioboranes is presented. Complex 1 demonstrated a great ability to catalyse the coupling of thiols with silanes and boranes under mild conditions with excellent results (turnover number up to 200)

Original language	English
Pages (from-to)	5829-5831
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	52
Early online date	23 May 2013
DOIs	https://doi.org/10.1039/c3cc43145b
Publication status	Published - 4 Jul 2013

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title = "Efficient ruthenium-catalysed S-S, S-Si and S-B bond forming reactions",

abstract = "[RuCl(PPh3)2(3-phenylindenyl)] (1) has been shown to be an efficient catalyst in thiol dehydrogenative coupling to give disulfides. Moreover, an efficient procedure for the preparation of silylthioethers and thioboranes is presented. Complex 1 demonstrated a great ability to catalyse the coupling of thiols with silanes and boranes under mild conditions with excellent results (turnover number up to 200)",

author = "{Fernandez Salas}, {Jose Antonio} and Simone Manzini and Nolan, {Steven Patrick}",

year = "2013",

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doi = "10.1039/c3cc43145b",

language = "English",

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journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Efficient ruthenium-catalysed S-S, S-Si and S-B bond forming reactions

AU - Fernandez Salas, Jose Antonio

AU - Manzini, Simone

AU - Nolan, Steven Patrick

PY - 2013/7/4

Y1 - 2013/7/4

N2 - [RuCl(PPh3)2(3-phenylindenyl)] (1) has been shown to be an efficient catalyst in thiol dehydrogenative coupling to give disulfides. Moreover, an efficient procedure for the preparation of silylthioethers and thioboranes is presented. Complex 1 demonstrated a great ability to catalyse the coupling of thiols with silanes and boranes under mild conditions with excellent results (turnover number up to 200)

AB - [RuCl(PPh3)2(3-phenylindenyl)] (1) has been shown to be an efficient catalyst in thiol dehydrogenative coupling to give disulfides. Moreover, an efficient procedure for the preparation of silylthioethers and thioboranes is presented. Complex 1 demonstrated a great ability to catalyse the coupling of thiols with silanes and boranes under mild conditions with excellent results (turnover number up to 200)

U2 - 10.1039/c3cc43145b

DO - 10.1039/c3cc43145b

M3 - Article

SN - 1359-7345

VL - 49

SP - 5829

EP - 5831

JO - Chemical Communications

JF - Chemical Communications

IS - 52

ER -

Efficient ruthenium-catalysed S-S, S-Si and S-B bond forming reactions

Abstract

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