Efficient ruthenium-catalysed S-S, S-Si and S-B bond forming reactions

Jose Antonio Fernandez Salas, Simone Manzini, Steven Patrick Nolan

Research output: Contribution to journalArticlepeer-review

32 Citations (Scopus)

Abstract

[RuCl(PPh3)2(3-phenylindenyl)] (1) has been shown to be an efficient catalyst in thiol dehydrogenative coupling to give disulfides. Moreover, an efficient procedure for the preparation of silylthioethers and thioboranes is presented. Complex 1 demonstrated a great ability to catalyse the coupling of thiols with silanes and boranes under mild conditions with excellent results (turnover number up to 200)
Original languageEnglish
Pages (from-to)5829-5831
Number of pages3
JournalChemical Communications
Volume49
Issue number52
Early online date23 May 2013
DOIs
Publication statusPublished - 4 Jul 2013

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