Efficient cross-coupling reactions of aryl chlorides and bromides with phenyl- or vinyltrimethoxysilane mediated by a palladium/imidazolium chloride system

H M  Lee; Steven Patrick Nolan

Efficient cross-coupling reactions of aryl chlorides and bromides with phenyl- or vinyltrimethoxysilane mediated by a palladium/imidazolium chloride system

H M Lee, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

GRAPHICS

A combination of palladium acetate and the imidazolium salt IPr-HCl (1, IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) has proven to be highly efficient in the cross coupling reactions of aryl bromides and electron deficient aryl chlorides with phenyltrimethoxysilane or vinyltrimethoxysilane. The catalytic performance of this system was found to be comparable to that of systems using PCy3 and P(o-tol)(3).

Original language	English
Pages (from-to)	2053-2055
Number of pages	3
Journal	Organic Letters
Volume	2
Issue number	14
Publication status	Published - 13 Jul 2000

Keywords

ALKYL GRIGNARD-REAGENTS
ORGANIC HALIDES
NICKEL
COMPLEXES
CARBENES
BIARYLS
DERIVATIVES
SECONDARY
CATALYSTS

Cite this

@article{77041bb7880b48a99215a5f331ea1a21,

title = "Efficient cross-coupling reactions of aryl chlorides and bromides with phenyl- or vinyltrimethoxysilane mediated by a palladium/imidazolium chloride system",

abstract = "GRAPHICSA combination of palladium acetate and the imidazolium salt IPr-HCl (1, IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) has proven to be highly efficient in the cross coupling reactions of aryl bromides and electron deficient aryl chlorides with phenyltrimethoxysilane or vinyltrimethoxysilane. The catalytic performance of this system was found to be comparable to that of systems using PCy3 and P(o-tol)(3).",

keywords = "ALKYL GRIGNARD-REAGENTS, ORGANIC HALIDES, NICKEL, COMPLEXES, CARBENES, BIARYLS, DERIVATIVES, SECONDARY, CATALYSTS",

author = "Lee, {H M} and Nolan, {Steven Patrick}",

year = "2000",

month = jul,

day = "13",

language = "English",

volume = "2",

pages = "2053--2055",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society (ACS)",

number = "14",

}

TY - JOUR

T1 - Efficient cross-coupling reactions of aryl chlorides and bromides with phenyl- or vinyltrimethoxysilane mediated by a palladium/imidazolium chloride system

AU - Lee, H M

AU - Nolan, Steven Patrick

PY - 2000/7/13

Y1 - 2000/7/13

N2 - GRAPHICSA combination of palladium acetate and the imidazolium salt IPr-HCl (1, IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) has proven to be highly efficient in the cross coupling reactions of aryl bromides and electron deficient aryl chlorides with phenyltrimethoxysilane or vinyltrimethoxysilane. The catalytic performance of this system was found to be comparable to that of systems using PCy3 and P(o-tol)(3).

AB - GRAPHICSA combination of palladium acetate and the imidazolium salt IPr-HCl (1, IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) has proven to be highly efficient in the cross coupling reactions of aryl bromides and electron deficient aryl chlorides with phenyltrimethoxysilane or vinyltrimethoxysilane. The catalytic performance of this system was found to be comparable to that of systems using PCy3 and P(o-tol)(3).

KW - ALKYL GRIGNARD-REAGENTS

KW - ORGANIC HALIDES

KW - NICKEL

KW - COMPLEXES

KW - CARBENES

KW - BIARYLS

KW - DERIVATIVES

KW - SECONDARY

KW - CATALYSTS

M3 - Article

SN - 1523-7060

VL - 2

SP - 2053

EP - 2055

JO - Organic Letters

JF - Organic Letters

IS - 14

ER -

Efficient cross-coupling reactions of aryl chlorides and bromides with phenyl- or vinyltrimethoxysilane mediated by a palladium/imidazolium chloride system

Abstract

Keywords

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