Efficiency of a ruthenium catalyst in metathesis reactions of sulfur-containing compounds

G  Spagnol; M P  Heck; Steven Patrick Nolan; C  Mioskowski

doi:10.1021/ol025834w

Efficiency of a ruthenium catalyst in metathesis reactions of sulfur-containing compounds

G Spagnol, M P Heck, Steven Patrick Nolan, C Mioskowski

Research output: Contribution to journal › Article › peer-review

Abstract

[GRAPHICS]

1,3-Dimesitylimidazol-2-ylidene ruthenium benzylidene catalyst (RuCl2(=C(H)Ph)(PCy3)(IMes)) has been successfully employed in ring-closing metathesis reactions of acyclic diene sulfides, disulfides, and dithianes and in self-cross metathesis reactions of ene-sulfides, thioethers, and thiols.

Original language	English
Pages (from-to)	1767-1770
Number of pages	4
Journal	Organic Letters
Volume	4
Issue number	10
DOIs	https://doi.org/10.1021/ol025834w
Publication status	Published - 16 May 2002

Keywords

RING-CLOSING-METATHESIS
OLEFIN METATHESIS
FUNCTIONALIZED OLEFINS
IMIDAZOLIN-2-YLIDENE LIGANDS
ALKYLIDENE COMPLEXES
CARBENE COMPLEXES
POLYCYCLIC ETHERS
DIENE METATHESIS
ACYCLIC OLEFINS
NEW-GENERATION

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10.1021/ol025834w

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title = "Efficiency of a ruthenium catalyst in metathesis reactions of sulfur-containing compounds",

abstract = "[GRAPHICS]1,3-Dimesitylimidazol-2-ylidene ruthenium benzylidene catalyst (RuCl2(=C(H)Ph)(PCy3)(IMes)) has been successfully employed in ring-closing metathesis reactions of acyclic diene sulfides, disulfides, and dithianes and in self-cross metathesis reactions of ene-sulfides, thioethers, and thiols.",

keywords = "RING-CLOSING-METATHESIS, OLEFIN METATHESIS, FUNCTIONALIZED OLEFINS, IMIDAZOLIN-2-YLIDENE LIGANDS, ALKYLIDENE COMPLEXES, CARBENE COMPLEXES, POLYCYCLIC ETHERS, DIENE METATHESIS, ACYCLIC OLEFINS, NEW-GENERATION",

author = "G Spagnol and Heck, {M P} and Nolan, {Steven Patrick} and C Mioskowski",

year = "2002",

month = may,

day = "16",

doi = "10.1021/ol025834w",

language = "English",

volume = "4",

pages = "1767--1770",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society (ACS)",

number = "10",

}

TY - JOUR

T1 - Efficiency of a ruthenium catalyst in metathesis reactions of sulfur-containing compounds

AU - Spagnol, G

AU - Heck, M P

AU - Nolan, Steven Patrick

AU - Mioskowski, C

PY - 2002/5/16

Y1 - 2002/5/16

N2 - [GRAPHICS]1,3-Dimesitylimidazol-2-ylidene ruthenium benzylidene catalyst (RuCl2(=C(H)Ph)(PCy3)(IMes)) has been successfully employed in ring-closing metathesis reactions of acyclic diene sulfides, disulfides, and dithianes and in self-cross metathesis reactions of ene-sulfides, thioethers, and thiols.

AB - [GRAPHICS]1,3-Dimesitylimidazol-2-ylidene ruthenium benzylidene catalyst (RuCl2(=C(H)Ph)(PCy3)(IMes)) has been successfully employed in ring-closing metathesis reactions of acyclic diene sulfides, disulfides, and dithianes and in self-cross metathesis reactions of ene-sulfides, thioethers, and thiols.

KW - RING-CLOSING-METATHESIS

KW - OLEFIN METATHESIS

KW - FUNCTIONALIZED OLEFINS

KW - IMIDAZOLIN-2-YLIDENE LIGANDS

KW - ALKYLIDENE COMPLEXES

KW - CARBENE COMPLEXES

KW - POLYCYCLIC ETHERS

KW - DIENE METATHESIS

KW - ACYCLIC OLEFINS

KW - NEW-GENERATION

U2 - 10.1021/ol025834w

DO - 10.1021/ol025834w

M3 - Article

SN - 1523-7060

VL - 4

SP - 1767

EP - 1770

JO - Organic Letters

JF - Organic Letters

IS - 10

ER -

Efficiency of a ruthenium catalyst in metathesis reactions of sulfur-containing compounds

Abstract

Keywords

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