Easy perchlorination of nitrogen-, oxygen-, fluorine-, silicon-, sulphur-, and tin-substituted aryl compounds

Christopher Glidewell, John C. Walton*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Aryl compounds containing a variety of heteroatomic substituents give good yields of the corresponding perchloro-derivatives when treated with a mixture of sulphur monochloride and anhydrous aluminium chloride in sulphuryl chloride solution; in aryl fluorides, such as hexafluorobenzene, considerable replacement of fluorine by chlorine takes place.

Original languageEnglish
Pages (from-to)915-916
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number24
DOIs
Publication statusPublished - 1 Dec 1977

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