(E)-3-Dimethylamino-2-(1H-indol-3-yl-carbonyl) acrylonitrile: a chain of edge-fused rings built from a three-centre N-H center dot center dot center dot( N,O) hydrogen bond

Jaime Galvez; Jairo Quiroga; Justo Cobo; John N. Low; Christopher Glidewell

doi:10.1107/S0108270108016417

(E)-3-Dimethylamino-2-(1H-indol-3-yl-carbonyl) acrylonitrile: a chain of edge-fused rings built from a three-centre N-H center dot center dot center dot( N,O) hydrogen bond

Jaime Galvez, Jairo Quiroga, Justo Cobo, John N. Low, Christopher Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, C14H13N3O, the intramolecular distances provide evidence for polarization of the molecular-electronic structure. A single three-centre N-H center dot center dot center dot(N,O) hydrogen bond links the molecules into chains of edge-fused R-2(2)(16) and R-2(4)(12) rings. Comparison with a number of related structures identifies factors of significance controlling the pattern of supramolecular aggregation.

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	64
DOIs	https://doi.org/10.1107/S0108270108016417
Publication status	Published - Jul 2008

Keywords

X-RAY
INDOLYLPYRIMIDINES

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10.1107/S0108270108016417

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@article{8be72b89510a45368854fef5931087e9,

title = "(E)-3-Dimethylamino-2-(1H-indol-3-yl-carbonyl) acrylonitrile: a chain of edge-fused rings built from a three-centre N-H center dot center dot center dot( N,O) hydrogen bond",

abstract = "In the title compound, C14H13N3O, the intramolecular distances provide evidence for polarization of the molecular-electronic structure. A single three-centre N-H center dot center dot center dot(N,O) hydrogen bond links the molecules into chains of edge-fused R-2(2)(16) and R-2(4)(12) rings. Comparison with a number of related structures identifies factors of significance controlling the pattern of supramolecular aggregation.",

keywords = "X-RAY, INDOLYLPYRIMIDINES",

author = "Jaime Galvez and Jairo Quiroga and Justo Cobo and Low, \{John N.\} and Christopher Glidewell",

year = "2008",

month = jul,

doi = "10.1107/S0108270108016417",

language = "English",

volume = "64",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

}

(E)-3-Dimethylamino-2-(1H-indol-3-yl-carbonyl) acrylonitrile: a chain of edge-fused rings built from a three-centre N-H center dot center dot center dot( N,O) hydrogen bond. / Galvez, Jaime; Quiroga, Jairo; Cobo, Justo et al.
In: Acta Crystallographica Section C-Crystal Structure Communications, Vol. 64, 07.2008.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - (E)-3-Dimethylamino-2-(1H-indol-3-yl-carbonyl) acrylonitrile: a chain of edge-fused rings built from a three-centre N-H center dot center dot center dot( N,O) hydrogen bond

AU - Galvez, Jaime

AU - Quiroga, Jairo

AU - Cobo, Justo

AU - Low, John N.

AU - Glidewell, Christopher

PY - 2008/7

Y1 - 2008/7

N2 - In the title compound, C14H13N3O, the intramolecular distances provide evidence for polarization of the molecular-electronic structure. A single three-centre N-H center dot center dot center dot(N,O) hydrogen bond links the molecules into chains of edge-fused R-2(2)(16) and R-2(4)(12) rings. Comparison with a number of related structures identifies factors of significance controlling the pattern of supramolecular aggregation.

AB - In the title compound, C14H13N3O, the intramolecular distances provide evidence for polarization of the molecular-electronic structure. A single three-centre N-H center dot center dot center dot(N,O) hydrogen bond links the molecules into chains of edge-fused R-2(2)(16) and R-2(4)(12) rings. Comparison with a number of related structures identifies factors of significance controlling the pattern of supramolecular aggregation.

KW - X-RAY

KW - INDOLYLPYRIMIDINES

UR - https://www.scopus.com/pages/publications/46749117296

U2 - 10.1107/S0108270108016417

DO - 10.1107/S0108270108016417

M3 - Article

SN - 1600-5759

SN - 0108-2701

VL - 64

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

(E)-3-Dimethylamino-2-(1H-indol-3-yl-carbonyl) acrylonitrile: a chain of edge-fused rings built from a three-centre N-H center dot center dot center dot( N,O) hydrogen bond

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