Abstract
In the title compound, C 16H 10Cl 2F 3N 3S, the dihedral angle between the quinoline and thio-phene ring systems is 4.94 (10)°. The NH group of the hydrazone moiety does not form a hydrogen bond, due to a steric crowding. In the crystal, the thio-phene ring takes part in weak π-π stacking inter-actions with the pyridine ring [centroid-to-centroid separation = 3.7553 (19) Å and inter-planar angle = 5.48 (12)°] and the benzene ring [3.7927 (19) Å and 4.58 (12)°]. Together, these lead to [100] stacks of mol-ecules in an alternating head-to-tail arrangement, with two π-π stacking contacts between each adjacent pair.
| Original language | English |
|---|---|
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 68 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - 1 Mar 2012 |
Keywords
- data-to-parameter ratio = 12.5
- mean σ(C-C) = 0.004 Å
- R factor = 0.049
- single-crystal X-ray study
- T = 73 K
- wR factor = 0.128
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