Dual NHC/photoredox catalytic synthesis of 1,4-diketones using an MR-TADF photocatalyst (DiKTa)

Callum Prentice, James Morrison, Eli Zysman-Colman*, Andrew D. Smith*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

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Abstract

The use of the recently reported organic multi-resonant thermally activated delayed fluorescence (MR-TADF) photocatalyst DiKTa allows for the modular synthesis of 1,4-diketones under mild and metal-free conditions. The reaction proceeds via a three-component relay process in the presence of an N-heterocyclic carbene (NHC) organocatalyst.
Original languageEnglish
Pages (from-to)13624-13627
Number of pages4
JournalChemical Communications
Volume58
Issue number98
Early online date11 Nov 2022
DOIs
Publication statusPublished - 21 Dec 2022

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