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Diversity in the haziness and chemistry of temperate sub-Neptunes

  • Pierre-Alexis Roy*
  • , Björn Benneke
  • , Marylou Fournier-Tondreau
  • , Louis-Philippe Coulombe
  • , Caroline Piaulet-Ghorayeb
  • , David Lafrenière
  • , Romain Allart
  • , Nicolas B. Cowan
  • , Lisa Dang
  • , Doug Johnstone
  • , Adam B. Langeveld
  • , Stefan Pelletier
  • , Michael Radica
  • , Jake Taylor
  • , Loïc Albert
  • , René Doyon
  • , Laura Flagg
  • , Ray Jayawardhana
  • , Ryan J. MacDonald
  • , Jake D. Turner
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Recent transit observations of K2-18 b and TOI-270 d revealed strong molecular absorption signatures, lending credence to the idea that temperate sub-Neptunes (equilibrium temperature Teq = 250–400 K) have upper atmospheres mostly free of aerosols. These observations also indicated higher-than-expected CO2 abundances on both planets, implying bulk compositions with high water mass fractions. However, it remains unclear whether these findings hold true for all temperate sub-Neptunes. Here we present the JWST NIRSpec/PRISM 0.7–5.4-μm transmission spectrum of a third temperate sub-Neptune, the 2.4 R planet LP 791-18 c (Teq = 355 K), which is even more favourable for atmospheric characterization thanks to its small M6 host star. Intriguingly, despite the radius, mass and equilibrium temperature of LP 791-18 c being between those of K2-18 b and TOI-270 d, we find a drastically different transmission spectrum. Although we also detect methane on LP 791-18 c, its transit spectrum is dominated by strong haze scattering and there is no discernible CO2 absorption. Overall, we infer a deep metal-enriched atmosphere (246–415 times solar) for LP 791-18 c, with a CO2-to-CH4 ratio smaller than 0.07 (at 2σ), indicating less H2O in the deep envelope of LP 791-18 c and implying a relatively dry formation inside the water-ice line. These results show that sub-Neptunes that are near analogues in density and temperature can show drastically different aerosols and envelope chemistry and are intrinsically diverse beyond a simple temperature dependence.
Original languageEnglish
Number of pages25
JournalNature Astronomy
VolumeAOP
Early online date12 Dec 2025
DOIs
Publication statusE-pub ahead of print - 12 Dec 2025

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