Diversity in the haziness and chemistry of temperate sub-Neptunes

Pierre-Alexis Roy*, Björn Benneke, Marylou Fournier-Tondreau, Louis-Philippe Coulombe, Caroline Piaulet-Ghorayeb, David Lafrenière, Romain Allart, Nicolas B. Cowan, Lisa Dang, Doug Johnstone, Adam B. Langeveld, Stefan Pelletier, Michael Radica, Jake Taylor, Loïc Albert, René Doyon, Laura Flagg, Ray Jayawardhana, Ryan J. MacDonald, Jake D. Turner

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Recent transit observations of K2-18 b and TOI-270 d revealed strong molecular absorption signatures, lending credence to the idea that temperate sub-Neptunes (equilibrium temperature Teq = 250–400 K) have upper atmospheres mostly free of aerosols. These observations also indicated higher-than-expected CO2 abundances on both planets, implying bulk compositions with high water mass fractions. However, it remains unclear whether these findings hold true for all temperate sub-Neptunes. Here we present the JWST NIRSpec/PRISM 0.7–5.4-μm transmission spectrum of a third temperate sub-Neptune, the 2.4 R planet LP 791-18 c (Teq = 355 K), which is even more favourable for atmospheric characterization thanks to its small M6 host star. Intriguingly, despite the radius, mass and equilibrium temperature of LP 791-18 c being between those of K2-18 b and TOI-270 d, we find a drastically different transmission spectrum. Although we also detect methane on LP 791-18 c, its transit spectrum is dominated by strong haze scattering and there is no discernible CO2 absorption. Overall, we infer a deep metal-enriched atmosphere (246–415 times solar) for LP 791-18 c, with a CO2-to-CH4 ratio smaller than 0.07 (at 2σ), indicating less H2O in the deep envelope of LP 791-18 c and implying a relatively dry formation inside the water-ice line. These results show that sub-Neptunes that are near analogues in density and temperature can show drastically different aerosols and envelope chemistry and are intrinsically diverse beyond a simple temperature dependence.
Original languageEnglish
Number of pages25
JournalNature Astronomy
VolumeAOP
Early online date12 Dec 2025
DOIs
Publication statusE-pub ahead of print - 12 Dec 2025

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