Divergent approach to imino sugar C-glycosides using imino glycols; application to the stereocontrolled synthesis of (+)-deoxoprosophyline

PJ Dransfield; PM Gore; M Shipman; Alexandra Martha Zoya Slawin

Divergent approach to imino sugar C-glycosides using imino glycols; application to the stereocontrolled synthesis of (+)-deoxoprosophyline

PJ Dransfield, PM Gore, M Shipman, Alexandra Martha Zoya Slawin

Research output: Other contribution

Abstract

Tri-O-acetyl imino glucal 2 is readily made and shown to undergo a variety of Lewis acid mediated carbon-carbon bond forming reactions at C-1 of the piperidine nucleus. In all the reactions studied, the beta-anomer is predominant.

Original language	English
Publication status	Published - 2002

Keywords

(+)-DESOXOPROSOPHYLLINE
ALKYLATION

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@misc{b536e04b5d574e94bfca70270fe4553e,

title = "Divergent approach to imino sugar C-glycosides using imino glycols; application to the stereocontrolled synthesis of (+)-deoxoprosophyline",

abstract = "Tri-O-acetyl imino glucal 2 is readily made and shown to undergo a variety of Lewis acid mediated carbon-carbon bond forming reactions at C-1 of the piperidine nucleus. In all the reactions studied, the beta-anomer is predominant.",

keywords = "(+)-DESOXOPROSOPHYLLINE, ALKYLATION",

author = "PJ Dransfield and PM Gore and M Shipman and Slawin, \{Alexandra Martha Zoya\}",

note = "Chem Comm",

year = "2002",

language = "English",

type = "Other",

}

TY - GEN

T1 - Divergent approach to imino sugar C-glycosides using imino glycols; application to the stereocontrolled synthesis of (+)-deoxoprosophyline

AU - Dransfield, PJ

AU - Gore, PM

AU - Shipman, M

AU - Slawin, Alexandra Martha Zoya

N1 - Chem Comm

PY - 2002

Y1 - 2002

N2 - Tri-O-acetyl imino glucal 2 is readily made and shown to undergo a variety of Lewis acid mediated carbon-carbon bond forming reactions at C-1 of the piperidine nucleus. In all the reactions studied, the beta-anomer is predominant.

AB - Tri-O-acetyl imino glucal 2 is readily made and shown to undergo a variety of Lewis acid mediated carbon-carbon bond forming reactions at C-1 of the piperidine nucleus. In all the reactions studied, the beta-anomer is predominant.

KW - (+)-DESOXOPROSOPHYLLINE

KW - ALKYLATION

M3 - Other contribution

ER -

Divergent approach to imino sugar C-glycosides using imino glycols; application to the stereocontrolled synthesis of (+)-deoxoprosophyline

Abstract

Keywords

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