(Disulfur dinitrido)triphenylantimony(V)

Alexandra M. Z. Slawin; Paul G. Waddell; J. Derek Woollins

doi:10.1107/S1600536810009487

(Disulfur dinitrido)triphenylantimony(V)

Alexandra M. Z. Slawin, Paul G. Waddell, J. Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Sb(C6H5)(3)(N2S2)], contains a molecular entity that is very similar to that of the known polymorph of Sb(S2N2)Ph-3 [Kunkel et al. (1997). Z. Naturforsch. Teil B, 52, 193-198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S-N=S=N, consisting of one long S-N bond, an intermediate length N=S bond and a short S=N bond.

Original language	English
Pages (from-to)	M418-U768
Number of pages	8
Journal	Acta Crystallographica. Section E, Structure reports online
Volume	66
Issue number	4
DOIs	https://doi.org/10.1107/S1600536810009487
Publication status	Published - Apr 2010

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ActaCrystE66 m418
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title = "(Disulfur dinitrido)triphenylantimony(V)",

abstract = "The title compound, [Sb(C6H5)(3)(N2S2)], contains a molecular entity that is very similar to that of the known polymorph of Sb(S2N2)Ph-3 [Kunkel et al. (1997). Z. Naturforsch. Teil B, 52, 193-198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S-N=S=N, consisting of one long S-N bond, an intermediate length N=S bond and a short S=N bond.",

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N2 - The title compound, [Sb(C6H5)(3)(N2S2)], contains a molecular entity that is very similar to that of the known polymorph of Sb(S2N2)Ph-3 [Kunkel et al. (1997). Z. Naturforsch. Teil B, 52, 193-198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S-N=S=N, consisting of one long S-N bond, an intermediate length N=S bond and a short S=N bond.

AB - The title compound, [Sb(C6H5)(3)(N2S2)], contains a molecular entity that is very similar to that of the known polymorph of Sb(S2N2)Ph-3 [Kunkel et al. (1997). Z. Naturforsch. Teil B, 52, 193-198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S-N=S=N, consisting of one long S-N bond, an intermediate length N=S bond and a short S=N bond.

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DO - 10.1107/S1600536810009487

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JF - Acta Crystallographica. Section E, Structure reports online

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(Disulfur dinitrido)triphenylantimony(V)

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