Dissolving alkali metals in zeolites: Genesis of the perfect cluster crystal

L J  Woodall; P A  Anderson; A R  Armstrong; P P  Edwards

Dissolving alkali metals in zeolites: Genesis of the perfect cluster crystal

L J Woodall, P A Anderson, A R Armstrong, P P Edwards

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The interaction of alkali metals with dehydrated zeolites Y and A leads, in a process which bears many similarities to the dissolution of those metals in non-aqueous liquid solvemts, to the formation of inclusion compounds which may be regarded as ordered arrays of closely spaced clusters, and whose properties are dependent on interactions between the clusters. A combined analysis of electron spin resonance, magnetic susceptibility and powder neutron diffraction results enabled us to follow in detail the chemistry behind the formation of sodium- and potassium-based 'cluster crystals' in zeolites Y and A respectively.

Original language	English
Pages (from-to)	719-727
Number of pages	9
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	5
Publication status	Published - 7 Mar 1996

Keywords

POTASSIUM CLUSTERS
IONIC CLUSTERS
LTA
SODALITE
SODIUM
CESIUM

Cite this

@article{1464020b8a6049ce915c06405b11b412,

title = "Dissolving alkali metals in zeolites: Genesis of the perfect cluster crystal",

abstract = "The interaction of alkali metals with dehydrated zeolites Y and A leads, in a process which bears many similarities to the dissolution of those metals in non-aqueous liquid solvemts, to the formation of inclusion compounds which may be regarded as ordered arrays of closely spaced clusters, and whose properties are dependent on interactions between the clusters. A combined analysis of electron spin resonance, magnetic susceptibility and powder neutron diffraction results enabled us to follow in detail the chemistry behind the formation of sodium- and potassium-based 'cluster crystals' in zeolites Y and A respectively.",

keywords = "POTASSIUM CLUSTERS, IONIC CLUSTERS, LTA, SODALITE, SODIUM, CESIUM",

author = "Woodall, \{L J\} and Anderson, \{P A\} and Armstrong, \{A R\} and Edwards, \{P P\}",

year = "1996",

month = mar,

day = "7",

language = "English",

pages = "719--727",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "5",

}

TY - JOUR

T1 - Dissolving alkali metals in zeolites: Genesis of the perfect cluster crystal

AU - Woodall, L J

AU - Anderson, P A

AU - Armstrong, A R

AU - Edwards, P P

PY - 1996/3/7

Y1 - 1996/3/7

N2 - The interaction of alkali metals with dehydrated zeolites Y and A leads, in a process which bears many similarities to the dissolution of those metals in non-aqueous liquid solvemts, to the formation of inclusion compounds which may be regarded as ordered arrays of closely spaced clusters, and whose properties are dependent on interactions between the clusters. A combined analysis of electron spin resonance, magnetic susceptibility and powder neutron diffraction results enabled us to follow in detail the chemistry behind the formation of sodium- and potassium-based 'cluster crystals' in zeolites Y and A respectively.

AB - The interaction of alkali metals with dehydrated zeolites Y and A leads, in a process which bears many similarities to the dissolution of those metals in non-aqueous liquid solvemts, to the formation of inclusion compounds which may be regarded as ordered arrays of closely spaced clusters, and whose properties are dependent on interactions between the clusters. A combined analysis of electron spin resonance, magnetic susceptibility and powder neutron diffraction results enabled us to follow in detail the chemistry behind the formation of sodium- and potassium-based 'cluster crystals' in zeolites Y and A respectively.

KW - POTASSIUM CLUSTERS

KW - IONIC CLUSTERS

KW - LTA

KW - SODALITE

KW - SODIUM

KW - CESIUM

UR - https://www.scopus.com/pages/publications/33748443845

M3 - Article

SN - 0300-9246

SP - 719

EP - 727

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 5

ER -

Dissolving alkali metals in zeolites: Genesis of the perfect cluster crystal

Abstract

Keywords

Other files and links

Fingerprint

Cite this