Dispirofluorene-indenofluorene derivatives as new building blocks for blue organic electroluminescent devices and electroactive polymers

Cyril Poriel; Jing-Jing Liang; Joelle Rault-Berthelot; Frederic Barriere; Nicolas Cocherel; Alexandra M. Z. Slawin; David Horhant; Morgane Virboul; Gilles Alcaraz; Nathalie Audebrand; Laurence Vignau; Nolwenn Huby; Guillaume Wantz; Lionel Hirsch

doi:10.1002/chem.200701036

Dispirofluorene-indenofluorene derivatives as new building blocks for blue organic electroluminescent devices and electroactive polymers

Cyril Poriel, Jing-Jing Liang, Joelle Rault-Berthelot, Frederic Barriere, Nicolas Cocherel, Alexandra M. Z. Slawin, David Horhant, Morgane Virboul, Gilles Alcaraz, Nathalie Audebrand, Laurence Vignau, Nolwenn Huby, Guillaume Wantz, Lionel Hirsch

Research output: Contribution to journal › Review article › peer-review

Abstract

A series of new dispiro[fluorene-9',6,9 '', 12-indeno[1,2b]fluorenes] (DSF-IFs) has been synthesised. These new building blocks for blue-light-emitting devices and electroactive polymers combine indenofluorene (IF) and spirobifluorene (SBF) properties. We report here our synthetic investigations towards these new structures and their thermal, structural, photophysical and electrochemical properties. These properties have been compared to those of IF and SBF We also report the anodic oxidation of DSF-IFs that leads to the formation of non-soluble transparent three-dimensional polymers. The structural and electrochemical behaviour of these polymers has been studied. The first application of these building blocks as new blue-light-emitting materials in organic light-emitting diodes (OLED) is also reported.

Original language	English
Pages (from-to)	10055-10069
Number of pages	15
Journal	Chemistry - A European Journal
Volume	13
Issue number	36
DOIs	https://doi.org/10.1002/chem.200701036
Publication status	Published - 2007

Keywords

cyclic voltammetry
dispirofluorene-indenofluorene
fluorescence
light-emitting diodes
polymers
LIGHT-EMITTING-DIODES
PRONOUNCED THERMAL-STABILITY
END-CAPPED OLIGOFLUORENES
PHYSICOCHEMICAL PROPERTIES
ELECTROCHEMICAL-BEHAVIOR
FUNCTIONAL-PROPERTIES
CONJUGATED OLIGOMERS
PHYSICAL-PROPERTIES
OPTICAL-PROPERTIES
CRYSTAL-STRUCTURE

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10.1002/chem.200701036

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Poriel, C., Liang, J.-J., Rault-Berthelot, J., Barriere, F., Cocherel, N., Slawin, A. M. Z., Horhant, D., Virboul, M., Alcaraz, G., Audebrand, N., Vignau, L., Huby, N., Wantz, G., & Hirsch, L. (2007). Dispirofluorene-indenofluorene derivatives as new building blocks for blue organic electroluminescent devices and electroactive polymers. Chemistry - A European Journal, 13(36), 10055-10069. https://doi.org/10.1002/chem.200701036

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title = "Dispirofluorene-indenofluorene derivatives as new building blocks for blue organic electroluminescent devices and electroactive polymers",

abstract = "A series of new dispiro[fluorene-9',6,9 '', 12-indeno[1,2b]fluorenes] (DSF-IFs) has been synthesised. These new building blocks for blue-light-emitting devices and electroactive polymers combine indenofluorene (IF) and spirobifluorene (SBF) properties. We report here our synthetic investigations towards these new structures and their thermal, structural, photophysical and electrochemical properties. These properties have been compared to those of IF and SBF We also report the anodic oxidation of DSF-IFs that leads to the formation of non-soluble transparent three-dimensional polymers. The structural and electrochemical behaviour of these polymers has been studied. The first application of these building blocks as new blue-light-emitting materials in organic light-emitting diodes (OLED) is also reported.",

keywords = "cyclic voltammetry, dispirofluorene-indenofluorene, fluorescence, light-emitting diodes, polymers, LIGHT-EMITTING-DIODES, PRONOUNCED THERMAL-STABILITY, END-CAPPED OLIGOFLUORENES, PHYSICOCHEMICAL PROPERTIES, ELECTROCHEMICAL-BEHAVIOR, FUNCTIONAL-PROPERTIES, CONJUGATED OLIGOMERS, PHYSICAL-PROPERTIES, OPTICAL-PROPERTIES, CRYSTAL-STRUCTURE",

author = "Cyril Poriel and Jing-Jing Liang and Joelle Rault-Berthelot and Frederic Barriere and Nicolas Cocherel and Slawin, {Alexandra M. Z.} and David Horhant and Morgane Virboul and Gilles Alcaraz and Nathalie Audebrand and Laurence Vignau and Nolwenn Huby and Guillaume Wantz and Lionel Hirsch",

year = "2007",

doi = "10.1002/chem.200701036",

language = "English",

volume = "13",

pages = "10055--10069",

journal = "Chemistry - A European Journal",

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publisher = "John Wiley & Sons, Ltd",

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Poriel, C, Liang, J-J, Rault-Berthelot, J, Barriere, F, Cocherel, N, Slawin, AMZ, Horhant, D, Virboul, M, Alcaraz, G, Audebrand, N, Vignau, L, Huby, N, Wantz, G & Hirsch, L 2007, 'Dispirofluorene-indenofluorene derivatives as new building blocks for blue organic electroluminescent devices and electroactive polymers', Chemistry - A European Journal, vol. 13, no. 36, pp. 10055-10069. https://doi.org/10.1002/chem.200701036

TY - JOUR

T1 - Dispirofluorene-indenofluorene derivatives as new building blocks for blue organic electroluminescent devices and electroactive polymers

AU - Poriel, Cyril

AU - Liang, Jing-Jing

AU - Rault-Berthelot, Joelle

AU - Barriere, Frederic

AU - Cocherel, Nicolas

AU - Slawin, Alexandra M. Z.

AU - Horhant, David

AU - Virboul, Morgane

AU - Alcaraz, Gilles

AU - Audebrand, Nathalie

AU - Vignau, Laurence

AU - Huby, Nolwenn

AU - Wantz, Guillaume

AU - Hirsch, Lionel

PY - 2007

Y1 - 2007

N2 - A series of new dispiro[fluorene-9',6,9 '', 12-indeno[1,2b]fluorenes] (DSF-IFs) has been synthesised. These new building blocks for blue-light-emitting devices and electroactive polymers combine indenofluorene (IF) and spirobifluorene (SBF) properties. We report here our synthetic investigations towards these new structures and their thermal, structural, photophysical and electrochemical properties. These properties have been compared to those of IF and SBF We also report the anodic oxidation of DSF-IFs that leads to the formation of non-soluble transparent three-dimensional polymers. The structural and electrochemical behaviour of these polymers has been studied. The first application of these building blocks as new blue-light-emitting materials in organic light-emitting diodes (OLED) is also reported.

AB - A series of new dispiro[fluorene-9',6,9 '', 12-indeno[1,2b]fluorenes] (DSF-IFs) has been synthesised. These new building blocks for blue-light-emitting devices and electroactive polymers combine indenofluorene (IF) and spirobifluorene (SBF) properties. We report here our synthetic investigations towards these new structures and their thermal, structural, photophysical and electrochemical properties. These properties have been compared to those of IF and SBF We also report the anodic oxidation of DSF-IFs that leads to the formation of non-soluble transparent three-dimensional polymers. The structural and electrochemical behaviour of these polymers has been studied. The first application of these building blocks as new blue-light-emitting materials in organic light-emitting diodes (OLED) is also reported.

KW - cyclic voltammetry

KW - dispirofluorene-indenofluorene

KW - fluorescence

KW - light-emitting diodes

KW - polymers

KW - LIGHT-EMITTING-DIODES

KW - PRONOUNCED THERMAL-STABILITY

KW - END-CAPPED OLIGOFLUORENES

KW - PHYSICOCHEMICAL PROPERTIES

KW - ELECTROCHEMICAL-BEHAVIOR

KW - FUNCTIONAL-PROPERTIES

KW - CONJUGATED OLIGOMERS

KW - PHYSICAL-PROPERTIES

KW - OPTICAL-PROPERTIES

KW - CRYSTAL-STRUCTURE

UR - http://www.scopus.com/inward/record.url?scp=38049135046&partnerID=8YFLogxK

U2 - 10.1002/chem.200701036

DO - 10.1002/chem.200701036

M3 - Review article

SN - 0947-6539

VL - 13

SP - 10055

EP - 10069

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 36

ER -

Dispirofluorene-indenofluorene derivatives as new building blocks for blue organic electroluminescent devices and electroactive polymers

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Keywords

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