Direct S-Arylation of Unactivated Arylsulfoxides Using [Pd(IPr*)(cin)Cl]

Frederic Izquierdo; Anthony Raymond Georges Chartoire; Steven Patrick Nolan

doi:10.1021/cs400533e

Direct S-Arylation of Unactivated Arylsulfoxides Using [Pd(IPr*)(cin)Cl]

Frederic Izquierdo, Anthony Raymond Georges Chartoire, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The direct S-arylation of unactivated arylsulfoxides catalyzed by [Pd(IPr*)(cin)Cl] is described. Several arylmethylsulfoxides were coupled to various aryl halides in
moderate to good yields (17 examples, 34−85%). Scope, limitations, and reaction mechanism are discussed.

Original language	English
Pages (from-to)	2190-2193
Number of pages	4
Journal	ACS Catalysis
Volume	3
Early online date	20 Aug 2013
DOIs	https://doi.org/10.1021/cs400533e
Publication status	Published - 2013

Keywords

palladium, N-heterocyclic carbenes (NHCs), arylation, sulfoxide, cross-coupling

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10.1021/cs400533e

N-heterocyclic carbenes in palladium-catalysed cross-coupling reactions
Izquierdo, F. (Author), Florence, G. J. (Supervisor) & Nolan, S. P. (Supervisor), 7 Dec 2017
Student thesis: Doctoral Thesis (PhD)

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title = "Direct S-Arylation of Unactivated Arylsulfoxides Using [Pd(IPr*)(cin)Cl]",

abstract = "The direct S-arylation of unactivated arylsulfoxides catalyzed by [Pd(IPr*)(cin)Cl] is described. Several arylmethylsulfoxides were coupled to various aryl halides inmoderate to good yields (17 examples, 34−85%). Scope, limitations, and reaction mechanism are discussed.",

keywords = "palladium, N-heterocyclic carbenes (NHCs), arylation, sulfoxide, cross-coupling",

author = "Frederic Izquierdo and Chartoire, {Anthony Raymond Georges} and Nolan, {Steven Patrick}",

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doi = "10.1021/cs400533e",

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journal = "ACS Catalysis",

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publisher = "American Chemical Society (ACS)",

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AU - Izquierdo, Frederic

AU - Chartoire, Anthony Raymond Georges

AU - Nolan, Steven Patrick

PY - 2013

Y1 - 2013

N2 - The direct S-arylation of unactivated arylsulfoxides catalyzed by [Pd(IPr*)(cin)Cl] is described. Several arylmethylsulfoxides were coupled to various aryl halides inmoderate to good yields (17 examples, 34−85%). Scope, limitations, and reaction mechanism are discussed.

AB - The direct S-arylation of unactivated arylsulfoxides catalyzed by [Pd(IPr*)(cin)Cl] is described. Several arylmethylsulfoxides were coupled to various aryl halides inmoderate to good yields (17 examples, 34−85%). Scope, limitations, and reaction mechanism are discussed.

KW - palladium, N-heterocyclic carbenes (NHCs), arylation, sulfoxide, cross-coupling

U2 - 10.1021/cs400533e

DO - 10.1021/cs400533e

M3 - Article

SN - 2155-5435

VL - 3

SP - 2190

EP - 2193

JO - ACS Catalysis

JF - ACS Catalysis

ER -

Direct S-Arylation of Unactivated Arylsulfoxides Using [Pd(IPr*)(cin)Cl]

Abstract

Keywords

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Student theses

N-heterocyclic carbenes in palladium-catalysed cross-coupling reactions

Cite this