Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation

Christin Kirst; Bela Ernest Bode; David Bradford Cordes; Phillip Nejman; Alexandra Martha Zoya Slawin; Konstantin Karaghiosoff; J Derek Woollins

doi:10.1039/C6DT00304D

Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation

Christin Kirst, Bela Ernest Bode, David Bradford Cordes, Phillip Nejman, Alexandra Martha Zoya Slawin, Konstantin Karaghiosoff , J Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

A convenient synthesis route to 2,2’-binaphtho[1,8-de][1,3,2]di-thiaphosphinine (3) was found. Its stable radical cation 3•+ was accessed easily through one-electron oxidation with NOBF4.

Original language	English
Pages (from-to)	6348-6351
Journal	Dalton Transactions
Volume	45
Issue number	15
Early online date	14 Mar 2016
DOIs	https://doi.org/10.1039/C6DT00304D
Publication status	Published - 21 Apr 2016

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Woollins_2016_DT_Diphosphane_AAM
Copyright 2016 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1039/C6DT00304D
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Woollins_2016_DT_Diphosphane_AAM_Supplementary
Copyright 2016 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1039/C6DT00304D
Accepted author manuscript, 1.1 MB

Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation (dataset)
Kirst, C. (Creator), Bode, B. E. (Creator), Cordes, D. B. (Creator), Nejman, P. (Creator), Slawin, A. M. Z. (Creator), Karaghiosoff , K. (Creator) & Woollins, J. D. (Creator), Cambridge Crystallographic Data Centre, 2015
https://dx.doi.org/10.5517/ccdc.csd.cc1kbckt and one more link, https://dx.doi.org/10.5517/ccdc.csd.cc1kbclv (show fewer)
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title = "Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation",

abstract = "A convenient synthesis route to 2,2{\textquoteright}-binaphtho[1,8-de][1,3,2]di-thiaphosphinine (3) was found. Its stable radical cation 3•+ was accessed easily through one-electron oxidation with NOBF4.",

author = "Christin Kirst and Bode, {Bela Ernest} and Cordes, {David Bradford} and Phillip Nejman and Slawin, {Alexandra Martha Zoya} and Konstantin Karaghiosoff and Woollins, {J Derek}",

year = "2016",

month = apr,

day = "21",

doi = "10.1039/C6DT00304D",

language = "English",

volume = "45",

pages = "6348--6351",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "ROYAL SOC CHEMISTRY",

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T1 - Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation

AU - Kirst, Christin

AU - Bode, Bela Ernest

AU - Cordes, David Bradford

AU - Nejman, Phillip

AU - Slawin, Alexandra Martha Zoya

AU - Karaghiosoff , Konstantin

AU - Woollins, J Derek

PY - 2016/4/21

Y1 - 2016/4/21

N2 - A convenient synthesis route to 2,2’-binaphtho[1,8-de][1,3,2]di-thiaphosphinine (3) was found. Its stable radical cation 3•+ was accessed easily through one-electron oxidation with NOBF4.

AB - A convenient synthesis route to 2,2’-binaphtho[1,8-de][1,3,2]di-thiaphosphinine (3) was found. Its stable radical cation 3•+ was accessed easily through one-electron oxidation with NOBF4.

U2 - 10.1039/C6DT00304D

DO - 10.1039/C6DT00304D

M3 - Article

SN - 1477-9226

VL - 45

SP - 6348

EP - 6351

JO - Dalton Transactions

JF - Dalton Transactions

IS - 15

ER -

Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation

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Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation (dataset)

Cite this