Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation

Christin Kirst, Bela Ernest Bode, David Bradford Cordes, Phillip Nejman, Alexandra Martha Zoya Slawin, Konstantin Karaghiosoff , J Derek Woollins

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)
4 Downloads (Pure)

Abstract

A convenient synthesis route to 2,2’-binaphtho[1,8-de][1,3,2]di-thiaphosphinine (3) was found. Its stable radical cation 3•+ was accessed easily through one-electron oxidation with NOBF4.
Original languageEnglish
Pages (from-to)6348-6351
JournalDalton Transactions
Volume45
Issue number15
Early online date14 Mar 2016
DOIs
Publication statusPublished - 21 Apr 2016

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