Diethyl pyrrole-2,5-dicarboxylate

R Alan Aitken; Charles Bloomfield; Liam J. R. McGeachie; Alexandra M. Z. Slawin

doi:10.3390/M1117

Diethyl pyrrole-2,5-dicarboxylate

R Alan Aitken^*, Charles Bloomfield, Liam J. R. McGeachie, Alexandra M. Z. Slawin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound has been obtained in moderate yield by a new and unexpected base-induced ring contraction from a 1,4-thiazine precursor. Its X-ray structure showing hydrogen bonded dimers is compared with those of other crystallographically characterized 2-acylpyrroles.

Original language	English
Article number	M1117
Number of pages	6
Journal	Molbank
Volume	2020
Issue number	1
DOIs	https://doi.org/10.3390/M1117
Publication status	Published - 17 Feb 2020

Keywords

Diethyl pyrrole-2,5-dicarboxylate
X-ray structure
Hydrogen bonding

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10.3390/M1117Licence: CC BY

Aitken_2020_Molbank_Diethyl_CC
Copyright © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
Final published version, 1.44 MBLicence: CC BY

Cite this

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title = "Diethyl pyrrole-2,5-dicarboxylate",

abstract = "The title compound has been obtained in moderate yield by a new and unexpected base-induced ring contraction from a 1,4-thiazine precursor. Its X-ray structure showing hydrogen bonded dimers is compared with those of other crystallographically characterized 2-acylpyrroles.",

keywords = "Diethyl pyrrole-2,5-dicarboxylate, X-ray structure, Hydrogen bonding",

author = "Aitken, {R Alan} and Charles Bloomfield and McGeachie, {Liam J. R.} and Slawin, {Alexandra M. Z.}",

year = "2020",

month = feb,

day = "17",

doi = "10.3390/M1117",

language = "English",

volume = "2020",

journal = "Molbank",

issn = "1422-8599",

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T1 - Diethyl pyrrole-2,5-dicarboxylate

AU - Aitken, R Alan

AU - Bloomfield, Charles

AU - McGeachie, Liam J. R.

AU - Slawin, Alexandra M. Z.

PY - 2020/2/17

Y1 - 2020/2/17

N2 - The title compound has been obtained in moderate yield by a new and unexpected base-induced ring contraction from a 1,4-thiazine precursor. Its X-ray structure showing hydrogen bonded dimers is compared with those of other crystallographically characterized 2-acylpyrroles.

AB - The title compound has been obtained in moderate yield by a new and unexpected base-induced ring contraction from a 1,4-thiazine precursor. Its X-ray structure showing hydrogen bonded dimers is compared with those of other crystallographically characterized 2-acylpyrroles.

KW - Diethyl pyrrole-2,5-dicarboxylate

KW - X-ray structure

KW - Hydrogen bonding

UR - https://www.mdpi.com/1422-8599/2020/1/M1117

U2 - 10.3390/M1117

DO - 10.3390/M1117

M3 - Article

SN - 1422-8599

VL - 2020

JO - Molbank

JF - Molbank

IS - 1

M1 - M1117

ER -

Diethyl pyrrole-2,5-dicarboxylate

Abstract

Keywords

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