Dichloro-μ2,μ2-naphthalene-1,8-diyl-bis(N,N,N’,N’-tetrameth- 2 ylethylenediamino)tetracopper(I)

Matthew James Ray; Maria L Saviantoni; Alexandra Martha Zoya Slawin; David Bradford Cordes; Petr Kilian

doi:10.3390/M1832

Dichloro-μ2,μ2-naphthalene-1,8-diyl-bis(N,N,N’,N’-tetrameth- 2 ylethylenediamino)tetracopper(I)

Matthew James Ray, Maria L Saviantoni, Alexandra Martha Zoya Slawin, David Bradford Cordes, Petr Kilian^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A highly reactive dicuprate/CuCl aggregate, Nap(Cu₄Cl₂)(TMEDA)₂ (2, Nap = naphthalene-1,8-diyl, TMEDA = tetramethylethylenediamine), was synthesized by the reaction of 1,8-dilithionaphthalene(TMEDA)₂ with four equivalents of CuCl. The X-ray crystal structure of this complex shows that the four copper atoms form a bent parallelogram-shaped core, with terminally bonded chlorine atoms. The naphthalene ring is bonded through carbons in the 1 and 8 positions (peri-positions), each bridging two copper atoms.

Original language	English
Article number	M1832
Number of pages	7
Journal	Molbank
Volume	2024
Issue number	2
DOIs	https://doi.org/10.3390/M1832
Publication status	Published - 5 Jun 2024

Keywords

Synthesis
Peri-substitution
Copper organometallic complex

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10.3390/M1832Licence: CC BY

Ray-2024-Dichloro-μ2,μ2-naphthalene-Molbank-2024-M1832-CCBY
Copyright: © 2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/4.0/).
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Dichloro-μ2,μ2-naphthalene-1,8-diyl-bis(N,N,N’,N’-tetramethylethylenediamino)tetracopper(I) (dataset)
Ray, M. J. (Contributor), Saviantoni , M. L. (Contributor), Slawin, A. M. Z. (Contributor), Cordes, D. B. (Contributor) & Kilian, P. (Supervisor), University of St Andrews, 6 Jun 2024
DOI: 10.17630/e44c6da7-cc54-4df3-a144-760386743bec
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title = "Dichloro-μ2,μ2-naphthalene-1,8-diyl-bis(N,N,N{\textquoteright},N{\textquoteright}-tetrameth- 2 ylethylenediamino)tetracopper(I)",

abstract = "A highly reactive dicuprate/CuCl aggregate, Nap(Cu4Cl2)(TMEDA)2 (2, Nap = naphthalene-1,8-diyl, TMEDA = tetramethylethylenediamine), was synthesized by the reaction of 1,8-dilithionaphthalene(TMEDA)2 with four equivalents of CuCl. The X-ray crystal structure of this complex shows that the four copper atoms form a bent parallelogram-shaped core, with terminally bonded chlorine atoms. The naphthalene ring is bonded through carbons in the 1 and 8 positions (peri-positions), each bridging two copper atoms.",

keywords = "Synthesis, Peri-substitution, Copper organometallic complex",

author = "Ray, {Matthew James} and Saviantoni, {Maria L} and Slawin, {Alexandra Martha Zoya} and Cordes, {David Bradford} and Petr Kilian",

year = "2024",

month = jun,

day = "5",

doi = "10.3390/M1832",

language = "English",

volume = "2024",

journal = "Molbank",

issn = "1422-8599",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

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TY - JOUR

T1 - Dichloro-μ2,μ2-naphthalene-1,8-diyl-bis(N,N,N’,N’-tetrameth- 2 ylethylenediamino)tetracopper(I)

AU - Ray, Matthew James

AU - Saviantoni, Maria L

AU - Slawin, Alexandra Martha Zoya

AU - Cordes, David Bradford

AU - Kilian, Petr

PY - 2024/6/5

Y1 - 2024/6/5

N2 - A highly reactive dicuprate/CuCl aggregate, Nap(Cu4Cl2)(TMEDA)2 (2, Nap = naphthalene-1,8-diyl, TMEDA = tetramethylethylenediamine), was synthesized by the reaction of 1,8-dilithionaphthalene(TMEDA)2 with four equivalents of CuCl. The X-ray crystal structure of this complex shows that the four copper atoms form a bent parallelogram-shaped core, with terminally bonded chlorine atoms. The naphthalene ring is bonded through carbons in the 1 and 8 positions (peri-positions), each bridging two copper atoms.

AB - A highly reactive dicuprate/CuCl aggregate, Nap(Cu4Cl2)(TMEDA)2 (2, Nap = naphthalene-1,8-diyl, TMEDA = tetramethylethylenediamine), was synthesized by the reaction of 1,8-dilithionaphthalene(TMEDA)2 with four equivalents of CuCl. The X-ray crystal structure of this complex shows that the four copper atoms form a bent parallelogram-shaped core, with terminally bonded chlorine atoms. The naphthalene ring is bonded through carbons in the 1 and 8 positions (peri-positions), each bridging two copper atoms.

KW - Synthesis

KW - Peri-substitution

KW - Copper organometallic complex

U2 - 10.3390/M1832

DO - 10.3390/M1832

M3 - Article

SN - 1422-8599

VL - 2024

JO - Molbank

JF - Molbank

IS - 2

M1 - M1832

ER -

Dichloro-μ2,μ2-naphthalene-1,8-diyl-bis(N,N,N’,N’-tetrameth- 2 ylethylenediamino)tetracopper(I)

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Dichloro-μ2,μ2-naphthalene-1,8-diyl-bis(N,N,N’,N’-tetramethylethylenediamino)tetracopper(I) (dataset)

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