TY - JOUR
T1 - Dicarboxylic acid esters from the carbonylation of unsaturated esters under mild conditions
AU - Jimenez-Rodriguez, C
AU - Eastham, G R
AU - Cole-Hamilton, D J
PY - 2005/10
Y1 - 2005/10
N2 - The methoxycarbonylation of unsaturated acids or esters catalysed by Pd complexes of bis(ditertiarybutyl-phosphinomethyl)benzene (DTBPMB) produces alpha,omega-diesters with selectivities >95%, even if the double bond is deep in the chain or conjugated to the carbonyl group; unsymmetrical esters can also be produced with high selectivity. (c) 2005 Elsevier B.V. All rights reserved.
AB - The methoxycarbonylation of unsaturated acids or esters catalysed by Pd complexes of bis(ditertiarybutyl-phosphinomethyl)benzene (DTBPMB) produces alpha,omega-diesters with selectivities >95%, even if the double bond is deep in the chain or conjugated to the carbonyl group; unsymmetrical esters can also be produced with high selectivity. (c) 2005 Elsevier B.V. All rights reserved.
KW - palladium
KW - methoxycarbonylation
KW - alpha,omega-diesters
KW - acrylic acids
KW - phosphine
UR - https://www.scopus.com/pages/publications/24944448712
U2 - 10.1016/j.inoche.2005.06.005
DO - 10.1016/j.inoche.2005.06.005
M3 - Article
SN - 1387-7003
VL - 8
SP - 878
EP - 881
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
ER -