Dicarboxylic acid esters from the carbonylation of unsaturated esters under mild conditions

C  Jimenez-Rodriguez; G R  Eastham; D J  Cole-Hamilton

doi:10.1016/j.inoche.2005.06.005

Dicarboxylic acid esters from the carbonylation of unsaturated esters under mild conditions

C Jimenez-Rodriguez, G R Eastham, D J Cole-Hamilton

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157 Citations (Scopus)

Abstract

The methoxycarbonylation of unsaturated acids or esters catalysed by Pd complexes of bis(ditertiarybutyl-phosphinomethyl)benzene (DTBPMB) produces alpha,omega-diesters with selectivities >95%, even if the double bond is deep in the chain or conjugated to the carbonyl group; unsymmetrical esters can also be produced with high selectivity. (c) 2005 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	878-881
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	8
DOIs	https://doi.org/10.1016/j.inoche.2005.06.005
Publication status	Published - Oct 2005

Keywords

palladium
methoxycarbonylation
alpha,omega-diesters
acrylic acids
phosphine

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10.1016/j.inoche.2005.06.005

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title = "Dicarboxylic acid esters from the carbonylation of unsaturated esters under mild conditions",

abstract = "The methoxycarbonylation of unsaturated acids or esters catalysed by Pd complexes of bis(ditertiarybutyl-phosphinomethyl)benzene (DTBPMB) produces alpha,omega-diesters with selectivities >95%, even if the double bond is deep in the chain or conjugated to the carbonyl group; unsymmetrical esters can also be produced with high selectivity. (c) 2005 Elsevier B.V. All rights reserved.",

keywords = "palladium, methoxycarbonylation, alpha,omega-diesters, acrylic acids, phosphine",

author = "C Jimenez-Rodriguez and Eastham, {G R} and Cole-Hamilton, {D J}",

year = "2005",

month = oct,

doi = "10.1016/j.inoche.2005.06.005",

language = "English",

volume = "8",

pages = "878--881",

journal = "Inorganic Chemistry Communications",

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T1 - Dicarboxylic acid esters from the carbonylation of unsaturated esters under mild conditions

AU - Jimenez-Rodriguez, C

AU - Eastham, G R

AU - Cole-Hamilton, D J

PY - 2005/10

Y1 - 2005/10

N2 - The methoxycarbonylation of unsaturated acids or esters catalysed by Pd complexes of bis(ditertiarybutyl-phosphinomethyl)benzene (DTBPMB) produces alpha,omega-diesters with selectivities >95%, even if the double bond is deep in the chain or conjugated to the carbonyl group; unsymmetrical esters can also be produced with high selectivity. (c) 2005 Elsevier B.V. All rights reserved.

AB - The methoxycarbonylation of unsaturated acids or esters catalysed by Pd complexes of bis(ditertiarybutyl-phosphinomethyl)benzene (DTBPMB) produces alpha,omega-diesters with selectivities >95%, even if the double bond is deep in the chain or conjugated to the carbonyl group; unsymmetrical esters can also be produced with high selectivity. (c) 2005 Elsevier B.V. All rights reserved.

KW - palladium

KW - methoxycarbonylation

KW - alpha,omega-diesters

KW - acrylic acids

KW - phosphine

UR - http://www.scopus.com/inward/record.url?scp=24944448712&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2005.06.005

DO - 10.1016/j.inoche.2005.06.005

M3 - Article

SN - 1387-7003

VL - 8

SP - 878

EP - 881

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Dicarboxylic acid esters from the carbonylation of unsaturated esters under mild conditions

Abstract

Keywords

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