Diazaphospholidine terminated polyhedral oligomeric silsesquioxanes in the hydroformylation of vinyl acetate

Nicolas R. Vautravers; David J. Cole-Hamilton

doi:10.1039/b814582b

Diazaphospholidine terminated polyhedral oligomeric silsesquioxanes in the hydroformylation of vinyl acetate

Nicolas R. Vautravers, David J. Cole-Hamilton

Research output: Contribution to journal › Article › peer-review

Abstract

The poorly active, monodentate SemiEsphos phosphine has been turned into an active ligand for rhodium catalysed vinyl acetate hydroformylation by attachment to the periphery of a polyhedral oligomeric silsesquioxane.

Original language	English
Pages (from-to)	92-94
Number of pages	3
Journal	Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/b814582b
Publication status	Published - 2009

Keywords

ASYMMETRIC HYDROFORMYLATION
MOLECULAR-DYNAMICS
DENDRIMERS
LIGANDS
RHODIUM
CATALYSIS

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10.1039/b814582b

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title = "Diazaphospholidine terminated polyhedral oligomeric silsesquioxanes in the hydroformylation of vinyl acetate",

abstract = "The poorly active, monodentate SemiEsphos phosphine has been turned into an active ligand for rhodium catalysed vinyl acetate hydroformylation by attachment to the periphery of a polyhedral oligomeric silsesquioxane.",

keywords = "ASYMMETRIC HYDROFORMYLATION, MOLECULAR-DYNAMICS, DENDRIMERS, LIGANDS, RHODIUM, CATALYSIS",

author = "Vautravers, {Nicolas R.} and Cole-Hamilton, {David J.}",

year = "2009",

doi = "10.1039/b814582b",

language = "English",

pages = "92--94",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "1",

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AU - Vautravers, Nicolas R.

AU - Cole-Hamilton, David J.

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KW - ASYMMETRIC HYDROFORMYLATION

KW - MOLECULAR-DYNAMICS

KW - DENDRIMERS

KW - LIGANDS

KW - RHODIUM

KW - CATALYSIS

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U2 - 10.1039/b814582b

DO - 10.1039/b814582b

M3 - Article

SN - 1359-7345

SP - 92

EP - 94

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

Diazaphospholidine terminated polyhedral oligomeric silsesquioxanes in the hydroformylation of vinyl acetate

Abstract

Keywords

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