Diazaphospholidine terminated polyhedral oligomeric silsesquioxanes in the hydroformylation of vinyl acetate

Nicolas R. Vautravers, David J. Cole-Hamilton

Research output: Contribution to journalArticlepeer-review

20 Citations (Scopus)

Abstract

The poorly active, monodentate SemiEsphos phosphine has been turned into an active ligand for rhodium catalysed vinyl acetate hydroformylation by attachment to the periphery of a polyhedral oligomeric silsesquioxane.

Original languageEnglish
Pages (from-to)92-94
Number of pages3
JournalChemical Communications
Issue number1
DOIs
Publication statusPublished - 2009

Keywords

  • ASYMMETRIC HYDROFORMYLATION
  • MOLECULAR-DYNAMICS
  • DENDRIMERS
  • LIGANDS
  • RHODIUM
  • CATALYSIS

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