TY - JOUR
T1 - Di-mu-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)]
AU - Slawin, Alexandra M. Z.
AU - Waddell, Paul G.
AU - Woollins, J. Derek
PY - 2010/5
Y1 - 2010/5
N2 - The title compound, [Pd2Cl4(C8H11O2P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd center dot center dot center dot Pd distance of 3.4662 (17) angstrom. It has a similar geometry to that observed in the triphenylphosphite and triphenylphosphine analogues. The Pd-P bond length is ca 0.04 angstrom shorter than those in mononuclear PdCl2(P(OMe)(2)Ph)(2), possibly due to the lower trans-influence of the bridging Cl- compared to a single-bonded Cl- atom.
AB - The title compound, [Pd2Cl4(C8H11O2P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd center dot center dot center dot Pd distance of 3.4662 (17) angstrom. It has a similar geometry to that observed in the triphenylphosphite and triphenylphosphine analogues. The Pd-P bond length is ca 0.04 angstrom shorter than those in mononuclear PdCl2(P(OMe)(2)Ph)(2), possibly due to the lower trans-influence of the bridging Cl- compared to a single-bonded Cl- atom.
UR - https://www.scopus.com/pages/publications/77952061781
U2 - 10.1107/S1600536810012055
DO - 10.1107/S1600536810012055
M3 - Article
SN - 1600-5368
VL - 66
SP - M499-U317
JO - Acta Crystallographica. Section E, Structure reports online
JF - Acta Crystallographica. Section E, Structure reports online
IS - 5
ER -