Di-mu-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)]

Alexandra M. Z. Slawin; Paul G. Waddell; J. Derek Woollins

doi:10.1107/S1600536810012055

Di-mu-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)]

Alexandra M. Z. Slawin, Paul G. Waddell, J. Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Pd2Cl4(C8H11O2P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd center dot center dot center dot Pd distance of 3.4662 (17) angstrom. It has a similar geometry to that observed in the triphenylphosphite and triphenylphosphine analogues. The Pd-P bond length is ca 0.04 angstrom shorter than those in mononuclear PdCl2(P(OMe)(2)Ph)(2), possibly due to the lower trans-influence of the bridging Cl- compared to a single-bonded Cl- atom.

Original language	English
Pages (from-to)	M499-U317
Number of pages	8
Journal	Acta Crystallographica. Section E, Structure reports online
Volume	66
Issue number	5
DOIs	https://doi.org/10.1107/S1600536810012055
Publication status	Published - May 2010

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ActaCrystE66 5 m499
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abstract = "The title compound, [Pd2Cl4(C8H11O2P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd center dot center dot center dot Pd distance of 3.4662 (17) angstrom. It has a similar geometry to that observed in the triphenylphosphite and triphenylphosphine analogues. The Pd-P bond length is ca 0.04 angstrom shorter than those in mononuclear PdCl2(P(OMe)(2)Ph)(2), possibly due to the lower trans-influence of the bridging Cl- compared to a single-bonded Cl- atom.",

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N2 - The title compound, [Pd2Cl4(C8H11O2P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd center dot center dot center dot Pd distance of 3.4662 (17) angstrom. It has a similar geometry to that observed in the triphenylphosphite and triphenylphosphine analogues. The Pd-P bond length is ca 0.04 angstrom shorter than those in mononuclear PdCl2(P(OMe)(2)Ph)(2), possibly due to the lower trans-influence of the bridging Cl- compared to a single-bonded Cl- atom.

AB - The title compound, [Pd2Cl4(C8H11O2P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd center dot center dot center dot Pd distance of 3.4662 (17) angstrom. It has a similar geometry to that observed in the triphenylphosphite and triphenylphosphine analogues. The Pd-P bond length is ca 0.04 angstrom shorter than those in mononuclear PdCl2(P(OMe)(2)Ph)(2), possibly due to the lower trans-influence of the bridging Cl- compared to a single-bonded Cl- atom.

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DO - 10.1107/S1600536810012055

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JO - Acta Crystallographica. Section E, Structure reports online

JF - Acta Crystallographica. Section E, Structure reports online

IS - 5

ER -

Di-mu-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)]

Abstract

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