Development of Novel Anode material for Intermediate Temperature SOFC (IT-SOFC)

Amit Sinha; David Noel Miller; John Thomas Sirr Irvine

doi:10.1039/C6TA03404G

Development of Novel Anode material for Intermediate Temperature SOFC (IT-SOFC)

Amit Sinha, David Noel Miller, John Thomas Sirr Irvine

Research output: Contribution to journal › Article › peer-review

Abstract

The present work envisages application of titanium oxycarbide as a possible anode material for intermediate temperature solid oxide fuel cells (IT-SOFC). Titanium oxycarbide samples (TiOxC1-x with x = 0.2 - 0.8) were prepared by reaction-sintering of TiO and TiC powders under vacuum at 1500 C for 5 h. Basic studies on TiOxC1-x (x = 0.2-0.8) with respect to phase purity and stability under oxidizing and reducing environments were carried out. The compatibility of titanium oxycarbide with intermediate-temperature electrolyte material (Ce0.9Gd0.1O3-δ) was studied. The electrochemical properties of planar cells using Ce0.9Gd0.1O3-δ as electrolyte and employing TiO0.2C0.8 and La0.8Sr0.2Co0.2Fe0.8O3-δ based anode and cathode materials were investigated.

Original language	English
Pages (from-to)	11117-11123
Number of pages	7
Journal	Journal of Materials Chemistry A
Volume	4
Issue number	28
Early online date	21 Jun 2016
DOIs	https://doi.org/10.1039/C6TA03404G
Publication status	Published - 28 Jul 2016

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10.1039/C6TA03404G

Development of novel anode material
Copyright © 2016, the Royal Society of Chemistry / the Author(s). This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1039/C6TA03404G
Accepted author manuscript, 1.7 MB

Energy Materials Discovery: Energy Materials Discovery Characterisation and Application
Irvine, J. T. S. (PI), Cassidy, M. (CoI), Connor, P. A. (CoI), Savaniu, C. D. (CoI) & Zhou, W. (CoI)
EPSRC
7/01/13 → 6/01/18
Project: Standard
Royal Society Wolfson Merit Award: Closing the Carbon Cycle with Solid State Electrochemistry
Irvine, J. T. S. (PI)
The Royal Society
1/08/12 → 31/07/17
Project: Standard
Hydrogen & Fuel Cells Supergen Hub: Hydrogen and Fuel Cells SUPERGEN Hub
Irvine, J. T. S. (PI)
EPSRC
1/05/12 → 30/04/17
Project: Standard

Cite this

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title = "Development of Novel Anode material for Intermediate Temperature SOFC (IT-SOFC)",

abstract = "The present work envisages application of titanium oxycarbide as a possible anode material for intermediate temperature solid oxide fuel cells (IT-SOFC). Titanium oxycarbide samples (TiOxC1-x with x = 0.2 - 0.8) were prepared by reaction-sintering of TiO and TiC powders under vacuum at 1500 C for 5 h. Basic studies on TiOxC1-x (x = 0.2-0.8) with respect to phase purity and stability under oxidizing and reducing environments were carried out. The compatibility of titanium oxycarbide with intermediate-temperature electrolyte material (Ce0.9Gd0.1O3-δ) was studied. The electrochemical properties of planar cells using Ce0.9Gd0.1O3-δ as electrolyte and employing TiO0.2C0.8 and La0.8Sr0.2Co0.2Fe0.8O3-δ based anode and cathode materials were investigated. ",

author = "Amit Sinha and Miller, {David Noel} and Irvine, {John Thomas Sirr}",

note = "We thank the Engineering and Physical Sciences Research Council (EPSRC)/ H2FC Supergen (EP/J016454/1, EP/K015540/1) and the Royal Society (WRMA 2012/R2) for support. ",

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doi = "10.1039/C6TA03404G",

language = "English",

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pages = "11117--11123",

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AU - Sinha, Amit

AU - Miller, David Noel

AU - Irvine, John Thomas Sirr

N1 - We thank the Engineering and Physical Sciences Research Council (EPSRC)/ H2FC Supergen (EP/J016454/1, EP/K015540/1) and the Royal Society (WRMA 2012/R2) for support.

PY - 2016/7/28

Y1 - 2016/7/28

N2 - The present work envisages application of titanium oxycarbide as a possible anode material for intermediate temperature solid oxide fuel cells (IT-SOFC). Titanium oxycarbide samples (TiOxC1-x with x = 0.2 - 0.8) were prepared by reaction-sintering of TiO and TiC powders under vacuum at 1500 C for 5 h. Basic studies on TiOxC1-x (x = 0.2-0.8) with respect to phase purity and stability under oxidizing and reducing environments were carried out. The compatibility of titanium oxycarbide with intermediate-temperature electrolyte material (Ce0.9Gd0.1O3-δ) was studied. The electrochemical properties of planar cells using Ce0.9Gd0.1O3-δ as electrolyte and employing TiO0.2C0.8 and La0.8Sr0.2Co0.2Fe0.8O3-δ based anode and cathode materials were investigated.

AB - The present work envisages application of titanium oxycarbide as a possible anode material for intermediate temperature solid oxide fuel cells (IT-SOFC). Titanium oxycarbide samples (TiOxC1-x with x = 0.2 - 0.8) were prepared by reaction-sintering of TiO and TiC powders under vacuum at 1500 C for 5 h. Basic studies on TiOxC1-x (x = 0.2-0.8) with respect to phase purity and stability under oxidizing and reducing environments were carried out. The compatibility of titanium oxycarbide with intermediate-temperature electrolyte material (Ce0.9Gd0.1O3-δ) was studied. The electrochemical properties of planar cells using Ce0.9Gd0.1O3-δ as electrolyte and employing TiO0.2C0.8 and La0.8Sr0.2Co0.2Fe0.8O3-δ based anode and cathode materials were investigated.

U2 - 10.1039/C6TA03404G

DO - 10.1039/C6TA03404G

M3 - Article

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VL - 4

SP - 11117

EP - 11123

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 28

ER -

Development of Novel Anode material for Intermediate Temperature SOFC (IT-SOFC)

Abstract

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Projects

Energy Materials Discovery: Energy Materials Discovery Characterisation and Application

Royal Society Wolfson Merit Award: Closing the Carbon Cycle with Solid State Electrochemistry

Hydrogen & Fuel Cells Supergen Hub: Hydrogen and Fuel Cells SUPERGEN Hub

Cite this