Deoxygenation of Pyridine N-Oxides by Palladium-Catalysed Transfer Oxidation of Trialkylamines

José A. Fuentes; Matthew L. Clarke

doi:10.1055/s-0028-1083508

Deoxygenation of Pyridine N-Oxides by Palladium-Catalysed Transfer Oxidation of Trialkylamines

Research output: Contribution to journal › Article › peer-review

Abstract

A convenient and chemoselective method for deoxygenation of pyridine N-oxide derivatives by transfer oxidation of triethylamine-catalysed by [Pd(OAc)(2)]/dppf is described.

Original language	English
Pages (from-to)	2579-2582
Number of pages	4
Journal	Synlett
Issue number	17
DOIs	https://doi.org/10.1055/s-0028-1083508
Publication status	Published - 21 Oct 2008

Keywords

deoxygenation
homogeneous catalysis
palladium
pyridine N-oxides
ligand effects
CHEMOSELECTIVE DEOXYGENATION
NITRO-COMPOUNDS
EFFICIENT
HYDROGENATION
REDUCTION
NITROALKANES
CONVERSION
COMPLEXES

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title = "Deoxygenation of Pyridine N-Oxides by Palladium-Catalysed Transfer Oxidation of Trialkylamines",

abstract = "A convenient and chemoselective method for deoxygenation of pyridine N-oxide derivatives by transfer oxidation of triethylamine-catalysed by [Pd(OAc)(2)]/dppf is described.",

keywords = "deoxygenation, homogeneous catalysis, palladium, pyridine N-oxides, ligand effects, CHEMOSELECTIVE DEOXYGENATION, NITRO-COMPOUNDS, EFFICIENT, HYDROGENATION, REDUCTION, NITROALKANES, CONVERSION, COMPLEXES",

author = "Fuentes, {Jos{\'e} A.} and Clarke, {Matthew L.}",

year = "2008",

month = oct,

day = "21",

doi = "10.1055/s-0028-1083508",

language = "English",

pages = "2579--2582",

journal = "Synlett",

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T1 - Deoxygenation of Pyridine N-Oxides by Palladium-Catalysed Transfer Oxidation of Trialkylamines

AU - Fuentes, José A.

AU - Clarke, Matthew L.

PY - 2008/10/21

Y1 - 2008/10/21

N2 - A convenient and chemoselective method for deoxygenation of pyridine N-oxide derivatives by transfer oxidation of triethylamine-catalysed by [Pd(OAc)(2)]/dppf is described.

AB - A convenient and chemoselective method for deoxygenation of pyridine N-oxide derivatives by transfer oxidation of triethylamine-catalysed by [Pd(OAc)(2)]/dppf is described.

KW - deoxygenation

KW - homogeneous catalysis

KW - palladium

KW - pyridine N-oxides

KW - ligand effects

KW - CHEMOSELECTIVE DEOXYGENATION

KW - NITRO-COMPOUNDS

KW - EFFICIENT

KW - HYDROGENATION

KW - REDUCTION

KW - NITROALKANES

KW - CONVERSION

KW - COMPLEXES

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U2 - 10.1055/s-0028-1083508

DO - 10.1055/s-0028-1083508

M3 - Article

SN - 0936-5214

SP - 2579

EP - 2582

JO - Synlett

JF - Synlett

IS - 17

ER -

Deoxygenation of Pyridine N-Oxides by Palladium-Catalysed Transfer Oxidation of Trialkylamines

Abstract

Keywords

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