Dendrimer bound tertiary phosphines for alkene hydroformylation

L Ropartz; Russell Edward Morris; GP Schwarz; DF Foster; David John Cole-Hamilton

Dendrimer bound tertiary phosphines for alkene hydroformylation

L Ropartz, Russell Edward Morris, GP Schwarz, DF Foster, David John Cole-Hamilton

Research output: Other contribution

Abstract

Dendrimer-based phosphines with 8, 24 and 72 PR2 arms (R = Me, Et. hexyl, Cy or Ph) based on polyhedral oligomeric silsesquioxane (POSS) cores have been synthesized and shown to catalyse hydroformylation reactions, in some cases with higher linear:branched product ratio (1:b) than their monomeric analogues. (C) 2000 Elsevier Science S.A. All rights reserved.

Original language	English
Volume	3
Publication status	Published - Dec 2000

Keywords

dendrimer
phosphine
rhodium
hydroformylation
alcohols
MEMBRANE REACTOR
FUNCTIONALIZED DENDRIMERS
CARBOSILANE DENDRIMERS
CATALYSTS
COMPLEXES
HYDROCARBONYLATION

Cite this

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title = "Dendrimer bound tertiary phosphines for alkene hydroformylation",

abstract = "Dendrimer-based phosphines with 8, 24 and 72 PR2 arms (R = Me, Et. hexyl, Cy or Ph) based on polyhedral oligomeric silsesquioxane (POSS) cores have been synthesized and shown to catalyse hydroformylation reactions, in some cases with higher linear:branched product ratio (1:b) than their monomeric analogues. (C) 2000 Elsevier Science S.A. All rights reserved.",

keywords = "dendrimer, phosphine, rhodium, hydroformylation, alcohols, MEMBRANE REACTOR, FUNCTIONALIZED DENDRIMERS, CARBOSILANE DENDRIMERS, CATALYSTS, COMPLEXES, HYDROCARBONYLATION",

author = "L Ropartz and Morris, {Russell Edward} and GP Schwarz and DF Foster and Cole-Hamilton, {David John}",

note = "Inorg Chem Commun",

year = "2000",

month = dec,

language = "English",

volume = "3",

type = "Other",

}

TY - GEN

T1 - Dendrimer bound tertiary phosphines for alkene hydroformylation

AU - Ropartz, L

AU - Morris, Russell Edward

AU - Schwarz, GP

AU - Foster, DF

AU - Cole-Hamilton, David John

N1 - Inorg Chem Commun

PY - 2000/12

Y1 - 2000/12

N2 - Dendrimer-based phosphines with 8, 24 and 72 PR2 arms (R = Me, Et. hexyl, Cy or Ph) based on polyhedral oligomeric silsesquioxane (POSS) cores have been synthesized and shown to catalyse hydroformylation reactions, in some cases with higher linear:branched product ratio (1:b) than their monomeric analogues. (C) 2000 Elsevier Science S.A. All rights reserved.

AB - Dendrimer-based phosphines with 8, 24 and 72 PR2 arms (R = Me, Et. hexyl, Cy or Ph) based on polyhedral oligomeric silsesquioxane (POSS) cores have been synthesized and shown to catalyse hydroformylation reactions, in some cases with higher linear:branched product ratio (1:b) than their monomeric analogues. (C) 2000 Elsevier Science S.A. All rights reserved.

KW - dendrimer

KW - phosphine

KW - rhodium

KW - hydroformylation

KW - alcohols

KW - MEMBRANE REACTOR

KW - FUNCTIONALIZED DENDRIMERS

KW - CARBOSILANE DENDRIMERS

KW - CATALYSTS

KW - COMPLEXES

KW - HYDROCARBONYLATION

UR - http://www.scopus.com/inward/record.url?scp=0034523841&partnerID=8YFLogxK

M3 - Other contribution

VL - 3

ER -

Dendrimer bound tertiary phosphines for alkene hydroformylation

Abstract

Keywords

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