Demonstration of reversible C-C bond cleavage in oxiranylcarbinyl radicals.

B A  Marples; J A  Rudderham; A M Z  Slawin; A J  Edwards; N W  Hird

Demonstration of reversible C-C bond cleavage in oxiranylcarbinyl radicals.

B A Marples, J A Rudderham, A M Z Slawin, A J Edwards, N W Hird

Research output: Contribution to journal › Article › peer-review

Abstract

The incorporation of a stereochemical probe into aryl substituted oxiranylcarbinyl radicals has demonstrated that the C-C bond cleavage in these systems is reversible, and that it can occur even when no products of C-C cleavage are obtained. (C) 1997 Elsevier Science Ltd.

Original language	English
Pages (from-to)	3599-3602
Number of pages	4
Journal	Tetrahedron Letters
Volume	38
Issue number	20
Publication status	Published - 19 May 1997

Keywords

INDUCED EPOXIDE FRAGMENTATION
ALPHA-IODOEPOXIDES
CHEMISTRY
CYCLOPENTANOLS
CARBOCYCLES

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title = "Demonstration of reversible C-C bond cleavage in oxiranylcarbinyl radicals.",

abstract = "The incorporation of a stereochemical probe into aryl substituted oxiranylcarbinyl radicals has demonstrated that the C-C bond cleavage in these systems is reversible, and that it can occur even when no products of C-C cleavage are obtained. (C) 1997 Elsevier Science Ltd.",

keywords = "INDUCED EPOXIDE FRAGMENTATION, ALPHA-IODOEPOXIDES, CHEMISTRY, CYCLOPENTANOLS, CARBOCYCLES",

author = "Marples, {B A} and Rudderham, {J A} and Slawin, {A M Z} and Edwards, {A J} and Hird, {N W}",

year = "1997",

month = may,

day = "19",

language = "English",

volume = "38",

pages = "3599--3602",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

number = "20",

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TY - JOUR

T1 - Demonstration of reversible C-C bond cleavage in oxiranylcarbinyl radicals.

AU - Marples, B A

AU - Rudderham, J A

AU - Slawin, A M Z

AU - Edwards, A J

AU - Hird, N W

PY - 1997/5/19

Y1 - 1997/5/19

N2 - The incorporation of a stereochemical probe into aryl substituted oxiranylcarbinyl radicals has demonstrated that the C-C bond cleavage in these systems is reversible, and that it can occur even when no products of C-C cleavage are obtained. (C) 1997 Elsevier Science Ltd.

AB - The incorporation of a stereochemical probe into aryl substituted oxiranylcarbinyl radicals has demonstrated that the C-C bond cleavage in these systems is reversible, and that it can occur even when no products of C-C cleavage are obtained. (C) 1997 Elsevier Science Ltd.

KW - INDUCED EPOXIDE FRAGMENTATION

KW - ALPHA-IODOEPOXIDES

KW - CHEMISTRY

KW - CYCLOPENTANOLS

KW - CARBOCYCLES

M3 - Article

SN - 0040-4039

VL - 38

SP - 3599

EP - 3602

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 20

ER -

Demonstration of reversible C-C bond cleavage in oxiranylcarbinyl radicals.

Abstract

Keywords

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