Demonstration of reversible C-C bond cleavage in oxiranylcarbinyl radicals.

B A Marples, J A Rudderham, A M Z Slawin, A J Edwards, N W Hird

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13 Citations (Scopus)

Abstract

The incorporation of a stereochemical probe into aryl substituted oxiranylcarbinyl radicals has demonstrated that the C-C bond cleavage in these systems is reversible, and that it can occur even when no products of C-C cleavage are obtained. (C) 1997 Elsevier Science Ltd.

Original languageEnglish
Pages (from-to)3599-3602
Number of pages4
JournalTetrahedron Letters
Volume38
Issue number20
Publication statusPublished - 19 May 1997

Keywords

  • INDUCED EPOXIDE FRAGMENTATION
  • ALPHA-IODOEPOXIDES
  • CHEMISTRY
  • CYCLOPENTANOLS
  • CARBOCYCLES

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