Demonstrating hydrogen production from ammonia using lithium imide - Powering a small proton exchange membrane fuel cell

Hazel M. A. Hunter; Joshua W. Makepeace; Thomas J. Wood; O. Simon Mylius; Mark G. Kibble; Jamie B. Nutter; Martin O. Jones; William I. F. David

doi:10.1016/j.jpowsour.2016.08.004

Demonstrating hydrogen production from ammonia using lithium imide - Powering a small proton exchange membrane fuel cell

Hazel M. A. Hunter^*, Joshua W. Makepeace, Thomas J. Wood, O. Simon Mylius, Mark G. Kibble, Jamie B. Nutter, Martin O. Jones, William I. F. David

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Accessing the intrinsic hydrogen content within ammonia, NH3, has the potential to play a very significant role in the future of a CO2-free sustainable energy supply. Inexpensive light metal imides and amides are effective at decomposing ammonia to hydrogen and nitrogen (2NH(3) -> 3H(2) + N-2), at modest temperatures, and thus represent a low-cost approach to on-demand hydrogen production. Building upon this discovery, this paper describes the integration of an ammonia cracking unit with a post-reactor gas purification system and a small-scale PEM fuel cell to create a first bench-top demonstrator for the production of hydrogen using light metal imides. (C) 2016 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	138-147
Number of pages	10
Journal	Journal of Power Sources
Volume	329
DOIs	https://doi.org/10.1016/j.jpowsour.2016.08.004
Publication status	Published - 15 Oct 2016

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Ammonia cracking
Demonstrator
Hydrogen production
PEM fuel cell
Lithium imide
Dead-ended anode
Performance
Adsorption

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@article{5cd0bb873ff04a3a801bad5ccf4d3f95,

title = "Demonstrating hydrogen production from ammonia using lithium imide - Powering a small proton exchange membrane fuel cell",

abstract = "Accessing the intrinsic hydrogen content within ammonia, NH3, has the potential to play a very significant role in the future of a CO2-free sustainable energy supply. Inexpensive light metal imides and amides are effective at decomposing ammonia to hydrogen and nitrogen (2NH(3) -> 3H(2) + N-2), at modest temperatures, and thus represent a low-cost approach to on-demand hydrogen production. Building upon this discovery, this paper describes the integration of an ammonia cracking unit with a post-reactor gas purification system and a small-scale PEM fuel cell to create a first bench-top demonstrator for the production of hydrogen using light metal imides. (C) 2016 Elsevier B.V. All rights reserved.",

keywords = "Ammonia cracking, Demonstrator, Hydrogen production, PEM fuel cell, Lithium imide, Dead-ended anode, Performance, Adsorption",

author = "Hunter, \{Hazel M. A.\} and Makepeace, \{Joshua W.\} and Wood, \{Thomas J.\} and Mylius, \{O. Simon\} and Kibble, \{Mark G.\} and Nutter, \{Jamie B.\} and Jones, \{Martin O.\} and David, \{William I. F.\}",

note = "This work was financially supported by an STFC Innovations Proof of Concept Award (POCF1213-14 Phase 3).",

year = "2016",

month = oct,

day = "15",

doi = "10.1016/j.jpowsour.2016.08.004",

language = "English",

volume = "329",

pages = "138--147",

journal = "Journal of Power Sources",

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T1 - Demonstrating hydrogen production from ammonia using lithium imide - Powering a small proton exchange membrane fuel cell

AU - Hunter, Hazel M. A.

AU - Makepeace, Joshua W.

AU - Wood, Thomas J.

AU - Mylius, O. Simon

AU - Kibble, Mark G.

AU - Nutter, Jamie B.

AU - Jones, Martin O.

AU - David, William I. F.

N1 - This work was financially supported by an STFC Innovations Proof of Concept Award (POCF1213-14 Phase 3).

PY - 2016/10/15

Y1 - 2016/10/15

N2 - Accessing the intrinsic hydrogen content within ammonia, NH3, has the potential to play a very significant role in the future of a CO2-free sustainable energy supply. Inexpensive light metal imides and amides are effective at decomposing ammonia to hydrogen and nitrogen (2NH(3) -> 3H(2) + N-2), at modest temperatures, and thus represent a low-cost approach to on-demand hydrogen production. Building upon this discovery, this paper describes the integration of an ammonia cracking unit with a post-reactor gas purification system and a small-scale PEM fuel cell to create a first bench-top demonstrator for the production of hydrogen using light metal imides. (C) 2016 Elsevier B.V. All rights reserved.

AB - Accessing the intrinsic hydrogen content within ammonia, NH3, has the potential to play a very significant role in the future of a CO2-free sustainable energy supply. Inexpensive light metal imides and amides are effective at decomposing ammonia to hydrogen and nitrogen (2NH(3) -> 3H(2) + N-2), at modest temperatures, and thus represent a low-cost approach to on-demand hydrogen production. Building upon this discovery, this paper describes the integration of an ammonia cracking unit with a post-reactor gas purification system and a small-scale PEM fuel cell to create a first bench-top demonstrator for the production of hydrogen using light metal imides. (C) 2016 Elsevier B.V. All rights reserved.

KW - Ammonia cracking

KW - Demonstrator

KW - Hydrogen production

KW - PEM fuel cell

KW - Lithium imide

KW - Dead-ended anode

KW - Performance

KW - Adsorption

UR - https://www.scopus.com/pages/publications/84983443921

U2 - 10.1016/j.jpowsour.2016.08.004

DO - 10.1016/j.jpowsour.2016.08.004

M3 - Article

SN - 0378-7753

VL - 329

SP - 138

EP - 147

JO - Journal of Power Sources

JF - Journal of Power Sources

ER -

Demonstrating hydrogen production from ammonia using lithium imide - Powering a small proton exchange membrane fuel cell

Abstract

UN SDGs

Keywords

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