Dehydropolymerization of H3B·NMeH2 Mediated by Cationic Iridium(III) Precatalysts Bearing κ3-iPr-PNRP Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism

CN Brodie, L Sotorrios, TM Boyd, SA Macgregor, AS Weller

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)
Original languageEnglish
Number of pages15
JournalACS Catalysis
Publication statusE-pub ahead of print - 12 Oct 2022


  • Amine-borane
  • Catalyst
  • Dehydropolymerization
  • Iridium
  • Kinetics
  • Mechanism
  • Metal-ligand cooperativity
  • Polymer

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