Dehydropolymerization of H3B·NMeH2 Mediated by Cationic Iridium(III) Precatalysts Bearing κ3-iPr-PNRP Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism

CN Brodie; L Sotorrios; TM Boyd; SA Macgregor; AS Weller

doi:10.1021/acscatal.2c03778

Dehydropolymerization of H₃B·NMeH₂ Mediated by Cationic Iridium(III) Precatalysts Bearing κ³-ⁱPr-PN^RP Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism

CN Brodie, L Sotorrios, TM Boyd, SA Macgregor, AS Weller

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Original language	English
Number of pages	15
Journal	ACS Catalysis
DOIs	https://doi.org/10.1021/acscatal.2c03778
Publication status	E-pub ahead of print - 12 Oct 2022

Keywords

Amine-borane
Catalyst
Dehydropolymerization
Iridium
Kinetics
Mechanism
Metal-ligand cooperativity
Polymer

Access to Document

10.1021/acscatal.2c03778

Cite this

@article{e1fe3f5a02a7460ab2b0586cb74d8814,

title = "Dehydropolymerization of H3B·NMeH2 Mediated by Cationic Iridium(III) Precatalysts Bearing κ3-iPr-PNRP Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism",

keywords = "Amine-borane, Catalyst, Dehydropolymerization, Iridium, Kinetics, Mechanism, Metal-ligand cooperativity, Polymer",

author = "CN Brodie and L Sotorrios and TM Boyd and SA Macgregor and AS Weller",

year = "2022",

month = oct,

day = "12",

doi = "10.1021/acscatal.2c03778",

language = "English",

journal = "ACS Catalysis",

issn = "2155-5435",

publisher = "American Chemical Society (ACS)",

}

TY - JOUR

T1 - Dehydropolymerization of H3B·NMeH2 Mediated by Cationic Iridium(III) Precatalysts Bearing κ3-iPr-PNRP Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism

AU - Brodie, CN

AU - Sotorrios, L

AU - Boyd, TM

AU - Macgregor, SA

AU - Weller, AS

PY - 2022/10/12

Y1 - 2022/10/12

KW - Amine-borane

KW - Catalyst

KW - Dehydropolymerization

KW - Iridium

KW - Kinetics

KW - Mechanism

KW - Metal-ligand cooperativity

KW - Polymer

UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=pure_st-andrews_wos_starter&SrcAuth=WosAPI&KeyUT=WOS:000870331500001&DestLinkType=FullRecord&DestApp=WOS_CPL

U2 - 10.1021/acscatal.2c03778

DO - 10.1021/acscatal.2c03778

M3 - Article

C2 - 36313521

SN - 2155-5435

JO - ACS Catalysis

JF - ACS Catalysis

ER -

Dehydropolymerization of H3B·NMeH2 Mediated by Cationic Iridium(III) Precatalysts Bearing κ3-iPr-PNRP Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism

Keywords

Access to Document

Other files and links

Cite this

Dehydropolymerization of H₃B·NMeH₂ Mediated by Cationic Iridium(III) Precatalysts Bearing κ³-ⁱPr-PN^RP Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism