Dehydrogenative boron homocoupling of an amine-borane

Heather C. Johnson; Claire L. McMullin; Sebastian D. Pike; Stuart A. Macgregor; Andrew S. Weller

doi:10.1002/anie.201304382

Dehydrogenative boron homocoupling of an amine-borane

Heather C. Johnson, Claire L. McMullin, Sebastian D. Pike, Stuart A. Macgregor^*, Andrew S. Weller

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A meeting of borons: The homocoupling of a B-B bond in an amine-borane is reported to give a diborane coordinated to a Rh^I metal center (see picture; C gray/black, O red, P blue, B green, N orange). The pathway for the occurrence of this reaction was also studied using density functional theory to calculate the free energies of each intermediate.

Original language	English
Pages (from-to)	9776-9780
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	37
DOIs	https://doi.org/10.1002/anie.201304382
Publication status	Published - 9 Sept 2013

Keywords

amine-borane
boron homocoupling
dehydrogenative coupling
rhodium
X-ray diffraction

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10.1002/anie.201304382

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abstract = "A meeting of borons: The homocoupling of a B-B bond in an amine-borane is reported to give a diborane coordinated to a RhI metal center (see picture; C gray/black, O red, P blue, B green, N orange). The pathway for the occurrence of this reaction was also studied using density functional theory to calculate the free energies of each intermediate.",

keywords = "amine-borane, boron homocoupling, dehydrogenative coupling, rhodium, X-ray diffraction",

author = "Johnson, \{Heather C.\} and McMullin, \{Claire L.\} and Pike, \{Sebastian D.\} and Macgregor, \{Stuart A.\} and Weller, \{Andrew S.\}",

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AU - Johnson, Heather C.

AU - McMullin, Claire L.

AU - Pike, Sebastian D.

AU - Macgregor, Stuart A.

AU - Weller, Andrew S.

PY - 2013/9/9

Y1 - 2013/9/9

N2 - A meeting of borons: The homocoupling of a B-B bond in an amine-borane is reported to give a diborane coordinated to a RhI metal center (see picture; C gray/black, O red, P blue, B green, N orange). The pathway for the occurrence of this reaction was also studied using density functional theory to calculate the free energies of each intermediate.

AB - A meeting of borons: The homocoupling of a B-B bond in an amine-borane is reported to give a diborane coordinated to a RhI metal center (see picture; C gray/black, O red, P blue, B green, N orange). The pathway for the occurrence of this reaction was also studied using density functional theory to calculate the free energies of each intermediate.

KW - amine-borane

KW - boron homocoupling

KW - dehydrogenative coupling

KW - rhodium

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/84883501392

U2 - 10.1002/anie.201304382

DO - 10.1002/anie.201304382

M3 - Article

AN - SCOPUS:84883501392

SN - 1433-7851

VL - 52

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EP - 9780

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 37

ER -

Dehydrogenative boron homocoupling of an amine-borane

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Keywords

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